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Alumina coatings doped with different precious metals were prepared by cathode plasma electrolytic deposition. Results show that the porosity of precious metal-doped alumina coatings (especially Al₂O₃-Ru) decreases, and the high-temperature cyclic oxidation resistance and spallation resistance are enhanced. The Al₂O₃-Ru composite coating shows better effect: its average oxidation rate K and average amount of oxide spallation G are minimum. Meanwhile, Nernst equation was used to explain the simultaneous deposition of precious metal and alumina, and the whole process and mechanism of deposition were analyzed.