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The brazing-ability of Al2O3P/Cu Base Metal Matrix Composite and Nb with AgCuTi filler metal was studied. The results show that through adding active element Ti to the filler metal, the Al2O3P grains in the brazing seam are decreased or eliminated, and the concentration of Al2O3P grains in the seam is avoided. The ionic bond Al2O3P is transformed in to metalloid bond TiO, so that the matching-ability of the brazing seam substrate and the grain phase is enhanced.