x,N1-x)基金屬陶瓷是用不同碳氮比制造的。研究了碳/氮比對芯-環(huán)結構和金屬陶瓷性能的影響。結果表明,由于孔太多, Ti(C0.5,N0.5)基金屬陶瓷的性能較差。隨著碳/氮比的增加,白核/灰環(huán)的形成率降低,并且微觀結構的均勻性增強。因此,基于 Ti(C0.7,N0.3)的金屬陶瓷顯示出優(yōu)異的力學性能,但有少量的孔隙和較低的相對密度。與Ti(C0.7,N0.3)基金屬陶瓷相比,TiC基金屬陶瓷在沒有N元素的情況下具有較高的相對密度且無孔隙,但其晶粒較粗大。為了獲得細晶粒和高密度的顯微組織,將0.25%Cr3C2-0.75%VC(質量分數(shù))引入到TiC基金屬陶瓷中,獲得了優(yōu)異的硬度、橫向斷裂強度和韌性。另外,在Ti(C0.7,N0.3)基金屬陶瓷中也添加了0.25%Cr3C2-0.75%VC,但其力學性能低于Ti(C0.7,N0.3)的金屬陶瓷,這是因為細顆粒和反應顆粒與Ti(C,N)發(fā)生了急性固溶反應。研究了基于不同C/N比的Ti(Cx,N1-x)基金屬陶瓷的切削性能和摩擦性能。結果表明,具有0.25%Cr2C3-0.75%VC的TiC基金屬陶瓷在室溫下的摩擦系數(shù)最低,為0.15,在1000 r/min的高速切削過程中,使用壽命最長。;Ti(Cx,N1-x)-based cermets are fabricated with different ratios of carbon to nitrogen. The effect of C/N ratio on the core-rim structures and properties of cermets was studied. The results indicate that Ti(C0.5,N0.5)-based cermets possess poor properties due to too many pores. With the increase of C/N ratio, the formation rate of white-core/gray-rims decreases, and the homogeneity of the microstructure is enhanced. Consequently, the Ti(C0.7,N0.3)-based cermets show excellent mechanical properties, but a spot of voids and low relative density. TiC-based cermets with excellent relative density and non-porosity can be achieved in the absence of N element, which have coarser grain compared with Ti(C0.7,N0.3)-based cermets. In order to achieve fine grains and high density microstructure, 0.25wt%Cr3C2-0.75wt%VC is introduced into the TiC-based cermets. Superior hardness, transverse rupture strength and toughness are achieved. In addition, 0.25wt%Cr3C2-0.75wt%VC is also added into the Ti(C0.7,N0.3)-based cermets, but its mechanical properties are lower than that of the Ti(C0.7,N0.3)-based cermets without 0.25wt%Cr3C2-0.75wt%VC addition, which is due to acute solid solution reaction of finer and reactive particles with Ti(C,N). The cutting and friction performances of Ti(Cx,N1-x)-based cermets with different C/N ratios were also investigated. The results show that the TiC-based cermets with 0.25wt%Cr3C2-0.75wt%VC exhibit the lowest coefficient of friction which is 0.15 at the room temperature, and the longest service life during high speed cutting at 1000 r/min."/>
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