2-CaO-Al2O3-MgO-TiO2這一低氟渣系和Incoloy825合金為例,綜述了電渣重熔過程中Al和Ti元素控制的研究現(xiàn)狀。應(yīng)用離子與分子共存理論(IMCT),結(jié)合FactSage軟件,總結(jié)了渣的熱力學(xué)和動力學(xué)研究方法。討論了溫度和渣成分對合金中平衡Al、Ti含量的影響?;谀B透理論,提出了預(yù)測合金中Al和Ti含量的動力學(xué)模型,得到了電渣過程中Al和Ti含量隨時間變化的數(shù)學(xué)方程式以及渣-金屬反應(yīng)速率的限制方法。確定電渣重熔Incoloy825合金時TiO2的最佳添加量約為10%。用IMCT和FactSage對渣-金平衡實驗結(jié)果進(jìn)行了比較和分析。FactSage計算結(jié)果比IMCT計算結(jié)果更準(zhǔn)確。TiO2含量越高,計算結(jié)果與實驗結(jié)果之間的偏差越小。;The oxidation of Al and Ti in the electroslag remelting process causes an uneven axial composition of the electroslag ingot, which adversely affects its performance, including corrosion resistance and mechanical properties. To control the uniformity of Al and Ti content in electroslag ingots, it is necessary to clarify the change in Al and Ti content during the high-temperature electroslag remelting and to reduce the oxidation of Al and Ti in the alloy by optimizing the slag system ratio and smelting conditions. The research status of Al and Ti element control in the electroslag remelting process was reviewed based on the existing literature, taking the low-fluorine slag CaF2-CaO-Al2O3-MgO-TiO2 and Incoloy 825 alloy as examples. The ion and molecular coexistence theory of slag (IMCT) was used along with FactSage software to summarize the thermodynamic and kinetic research methods. The effects of temperature and components of slag on the equilibrium Al and Ti contents in the alloy were discussed. Based on the film-penetration theory, a kinetics model for predicting Al and Ti contents in the alloy was proposed, and the mathematical equation of the Al and Ti contents vs time in the electroslag process and the slag-metal reaction rate-limiting method were obtained. Results show that the optimum TiO2 addition during the electroslag remelting for Incoloy 825 alloy is determined to be approximately 10%. The slag-metal equilibrium experimental results were compared and analyzed using IMCT and FactSage. It is found that the FactSage calculation results are more accurate than the IMCT calculation results. The higher the TiO2 content, the smaller the deviation between the calculated and experimental results."/>

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