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SiBNC陶瓷的制備與高溫行為研究
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國防科學技術大學新型陶瓷纖維及其復合材料重點實驗室,國防科學技術大學新型陶瓷纖維及其復合材料重點實驗室,國防科學技術大學新型陶瓷纖維及其復合材料重點實驗室

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Synthesis, Ceramic Conversion and High-temperature behavior of Polymer-derived SiBCN Ceramic
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Science and Technology on Advanced Ceramic Fibres and Composites Laboratory,National University of Defense Technology,Science and Technology on Advanced Ceramic Fibres and Composites Laboratory,National University of Defense Technology,Science and Technology on Advanced Ceramic Fibres and Composites Laboratory,National University of Defense Technology

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    摘要:

    本文通過六甲基二硅氮烷與二氯甲基硅烷和三氯化硼共聚縮合的方法,合成了SiBNC陶瓷先驅體。通過FT-IR與XPS對先驅體的化學組成與結構進行了表征,平面B-N單元與Si-N單元的隨機排列形成了以–Si-N-B-為骨架的理想先驅體結構。先驅體在氮氣氣氛下加熱到800°C后轉化成多元的SiBNC陶瓷,1000°C裂解后的陶瓷產率為50.1wt%。在氮氣氣氛下,得到的SiBNC陶瓷在1700°C下保持無定形,在1800°C下形成Si3N4 結晶。但在氬氣氣氛中,得到的SiBNC陶瓷在1800°C形成明顯的β-SiC 與BNC2結晶。

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    SiBNC preceramic polymer was synthesized by reacting hexamethyldisilazane simultaneously with dichoromethylsilane and trichoroborane in one pot. The prepared precursors were investigated with respect to their chemical and phase composition, by means of FT-IR and XPS. The random arrangement of planar B-N units and Si-N bonds formed the desired polymer precursors with –Si-N-B- framework. The precursor was converted into multinary ceramics when heated above 800°C with the yields of 50.1wt%. Under N2, the obtained SiBNC ceramic remained amorphous up to 1700 °C and formed crystallization of Si3N4 at 1800°C. But under Ar atmosphere, the sample showed obvious crystallization of β-SiC and BNC2 at 1800°C.

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紀小宇,邵長偉,王浩. SiBNC陶瓷的制備與高溫行為研究[J].稀有金屬材料與工程,2018,47(S2):149~152.[Xiaoyu Ji, Changwei Shao, Hao Wang. Synthesis, Ceramic Conversion and High-temperature behavior of Polymer-derived SiBCN Ceramic[J]. Rare Metal Materials and Engineering,2018,47(S2):149~152.]
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  • 收稿日期:2017-12-04
  • 最后修改日期:2017-12-04
  • 錄用日期:2018-02-01
  • 在線發(fā)布日期: 2018-11-01
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