2層逐漸變厚,纖維強度明顯降低。纖維在1200°C氧化1h后強度保留率為63%,表明在此溫度以下纖維有較好的服役性能。另一方面,氮化硅纖維在1450°C N2中處理1h的強度保留率為57%,表現(xiàn)出良好的耐高溫性能。纖維表面氧化對其在N2下的耐高溫性能具有不利影響,1000°C氧化的纖維在1450°C處理后喪失強度,1500℃處理后形成氮化硅結(jié)晶,失重明顯增長,纖維內(nèi)部也開始產(chǎn)生缺陷。"/>

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連續(xù)氮化硅纖維的氧化行為與高溫影響研究
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新型陶瓷纖維及其復(fù)合材料重點實驗室,新型陶瓷纖維及其復(fù)合材料重點實驗室,新型陶瓷纖維及其復(fù)合材料重點實驗室

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Effects of oxidative behavior on the strength and thermal resistance of continuous silicon nitride fibers
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Science and Technology on Advanced Ceramic Fibers and Composites Laboratory,National University of Defense Technology,Science and Technology on Advanced Ceramic Fibers and Composites Laboratory,National University of Defense Technology,Science and Technology on Advanced Ceramic Fibers and Composites Laboratory,National University of Defense Technology

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    摘要:

    連續(xù)氮化硅陶瓷纖維是透波/承載一體化陶瓷基復(fù)合材料的關(guān)鍵原材料,也是制約復(fù)合材料耐高溫性能與力學(xué)性能的關(guān)鍵因素。本文系統(tǒng)研究了國防科技大學(xué)研制的連續(xù)氮化硅纖維的抗氧化性能,分析了高溫處理后纖維的組成結(jié)構(gòu)與力學(xué)性能變化規(guī)律。結(jié)果表明:1000°C氧化1h后纖維強度高于原始纖維強度,主要是形成的玻璃相能減少和彌補纖維的表面缺陷。隨著空氣中處理溫度提高,氧含量增加,纖維表面形成的SiO2層逐漸變厚,纖維強度明顯降低。纖維在1200°C氧化1h后強度保留率為63%,表明在此溫度以下纖維有較好的服役性能。另一方面,氮化硅纖維在1450°C N2中處理1h的強度保留率為57%,表現(xiàn)出良好的耐高溫性能。纖維表面氧化對其在N2下的耐高溫性能具有不利影響,1000°C氧化的纖維在1450°C處理后喪失強度,1500℃處理后形成氮化硅結(jié)晶,失重明顯增長,纖維內(nèi)部也開始產(chǎn)生缺陷。

    Abstract:

    This study evaluates the oxidative resistance and the thermal stability in inert atmosphere of silicon nitride fibers. When the silicon nitride fibers were oxidized at 1000 °C for 1 h, they possessed the highest tensile strength (1.53 GPa) because of the surface defect healing effect of the glassy phase, whereas those oxidized at higher temperatures showed lower strength than the non-oxidized fibers. After treatment at 1200 °C in air, they retained 63% of strength, which indicates that the fiber might possess high serving life at the temperature lower than 1200 °C. Besides, the strength retention of the fibers after 1 h at 1450 °C in nitrogen remained 57%, showing good thermal stability. However, surface oxidation adversely affected the thermal stability of the fibers at high temperatures in nitrogen because of the predominant oxygen-containing phase. Above 1500 °C, crystallization of Si3N4 along with decomposition of SiNxOy occurred, resulting in a considerable decrease in weight and a catastrophic decrease in strength for the oxidized fibers.

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胡暄,邵長偉,王軍.連續(xù)氮化硅纖維的氧化行為與高溫影響研究[J].稀有金屬材料與工程,2018,47(S2):232~237.[Hu Xuan, Shao Changwei, Wang Jun. Effects of oxidative behavior on the strength and thermal resistance of continuous silicon nitride fibers[J]. Rare Metal Materials and Engineering,2018,47(S2):232~237.]
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  • 收稿日期:2017-12-01
  • 最后修改日期:2017-12-01
  • 錄用日期:2018-02-01
  • 在線發(fā)布日期: 2018-11-01
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