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石蠟/納米多孔二氧化硅復(fù)合材料的結(jié)構(gòu)與熱響應(yīng)
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長沙大學(xué)生物與環(huán)境工程學(xué)院

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Thermodynamic/heat transfer of n-eicosane in silica nano-porous materials
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College of Bio-engineering and Environmental Science , Changsha University

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    摘要:

    石蠟與納米尺度的多孔二氧化硅骨架之間緊密的復(fù)合結(jié)構(gòu)與熱特性在溫度調(diào)控管理與能源高效利用等方面展現(xiàn)了良好的應(yīng)用前景。用溶膠-凝膠工藝制備了納米多孔二氧化硅基體并采用相變材料熔體浸滲法制備納米相變復(fù)合材料,利用場發(fā)射掃描電鏡分析該復(fù)合材料的顯微結(jié)構(gòu),根據(jù)工程應(yīng)用條件進行組合的熱動力/熱傳輸計算,分析石蠟面積分?jǐn)?shù)對溫度調(diào)控的響應(yīng)關(guān)系。結(jié)果表明,石蠟的面積分?jǐn)?shù)與組件的溫度差呈現(xiàn)雙曲函數(shù)關(guān)系,即隨著石蠟在多孔二氧化硅骨架中面積分?jǐn)?shù)的增加,抑制溫度急劇變化的能力增強;石蠟面積分?jǐn)?shù)與總質(zhì)量和厚度呈單調(diào)遞減的關(guān)系。

    Abstract:

    The strong interaction between n-eicosane and silica nanoscale skeleton exhibits novel phase change temperature management and energy utilization. In this study, a sol-gel synthesized method to fabricate phase change nano-composites by impregnating silica nano-porous materials with n-eicosane is reported. Field emission scanning electron microscope (FE-SEM) results show that the sol-gel synthesized silica has an open network structure as a host for shape stabilization of molten n-eicosane. A combined thermodynamic/heat transfer analysis was carried out to determine the total mass, thickness, and temperature excursion as a function of the area fraction of n-eicosane at given maximum energy and thermal flux. The derived hyperbolic relations showed that increasing the n-eicosane area fraction resulted in a better thermal management in smoothing temperature fluctuation, lower total mass, and lower volume in the nano-composites.

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周祥發(fā).石蠟/納米多孔二氧化硅復(fù)合材料的結(jié)構(gòu)與熱響應(yīng)[J].稀有金屬材料與工程,2018,47(S2):223~227.[zhouxiangfa. Thermodynamic/heat transfer of n-eicosane in silica nano-porous materials[J]. Rare Metal Materials and Engineering,2018,47(S2):223~227.]
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  • 收稿日期:2017-11-30
  • 最后修改日期:2017-12-06
  • 錄用日期:2018-02-01
  • 在線發(fā)布日期: 2018-11-01
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