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多孔類石墨相氮化碳的制備及光催化性能研究
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浙江大學 材料科學與工程學院 硅材料國家重點實驗室,浙江大學 材料科學與工程學院 硅材料國家重點實驗室,浙江大學 材料科學與工程學院 硅材料國家重點實驗室,浙江大學 材料科學與工程學院 硅材料國家重點實驗室,浙江大學 材料科學與工程學院 硅材料國家重點實驗室,浙江大學 材料科學與工程學院 硅材料國家重點實驗室,浙江大學 材料科學與工程學院 硅材料國家重點實驗室

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Preparation of porous graphitic carbon nitride with en-hanced visible-light photocatalytic activities
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State Key Laboratory of Silicon Materials,School of Materials Science and Engineering,Zhejiang University,Hangzhou PR China,State Key Laboratory of Silicon Materials,School of Materials Science and Engineering,Zhejiang University,Hangzhou PR China,State Key Laboratory of Silicon Materials,School of Materials Science and Engineering,Zhejiang University,Hangzhou PR China,State Key Laboratory of Silicon Materials,School of Materials Science and Engineering,Zhejiang University,Hangzhou PR China,State Key Laboratory of Silicon Materials,School of Materials Science and Engineering,Zhejiang University,Hangzhou PR China,State Key Laboratory of Silicon Materials,School of Materials Science and Engineering,Zhejiang University,Hangzhou PR China,State Key Laboratory of Silicon Materials,School of Materials Science and Engineering,Zhejiang University,Hangzhou PR China

Fund Project:

The National Key Research and Development Program of China (No. 2016YFB0701100)

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    摘要:

    通過簡單的氨水水熱法制備得到了多孔g-C3N4光催化材料。利用 X 射線衍射(XRD)、紅外光譜(FT-IR)、掃描電子顯微鏡(SEM)、透射電子顯微鏡(TEM)研究了氨水對多孔g-C3N4結構的影響。并以亞甲基藍為目標分解物考察了樣品的可見光催化活性。研究結果表明:制備得到多孔g-C3N4具有由2D 納米片和相互連通的孔道組成的多孔納米結構。多孔g-C3N4的可見光催化活性得到了提升,原因在于相較于普通g-C3N4,多孔g-C3N4能夠提供更多的光催化反應活性位點,并且具有更高的光生載流子分離及遷移效率。

    Abstract:

    A simple and template-free synthesis method was developed to fabricate porous graphitic carbon nitride (g-C3N4) through a hydrothermal process in the presence of ammonium hydroxide. The effect of ammonium hydroxide on the structure of porous g-C3N4 was characterized in details by XRD, FT-IR, SEM and TEM. The photocatalytic activity of porous g-C3N4 was evaluated by the degradation of methylene blue (MB) under visible light irradiation. The results show that as-prepared porous g-C3N4 exhibits a porous nanostructure composed of 2D nanosheets and interconnected pores. The photocatalytic activity of porous g-C3N4 is enhanced, owing to the synergistic effect of more reaction sites and good separation efficiency of photo-generated carriers.

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尤增宇,蘇鈺璇,王輝,于洋,秦天,申乾宏,楊輝.多孔類石墨相氮化碳的制備及光催化性能研究[J].稀有金屬材料與工程,2018,47(S2):204~208.[YOU Zengyu, SU Yuxuan, WANG Hui, YU Yang, QIN Tian, SHEN Qianhong, YANG Hui. Preparation of porous graphitic carbon nitride with en-hanced visible-light photocatalytic activities[J]. Rare Metal Materials and Engineering,2018,47(S2):204~208.]
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  • 收稿日期:2017-11-28
  • 最后修改日期:2017-11-28
  • 錄用日期:2018-02-01
  • 在線發(fā)布日期: 2018-11-01
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