2WO6;Fe3O4;磁性光催化劑;復(fù)合物"/> 2WO6),結(jié)構(gòu)最簡單的Aurivillius相化合物,是近期受到研究者關(guān)注的新型光催化材料。然而,光催化劑粉末在反應(yīng)介質(zhì)中難被回收,工業(yè)化應(yīng)用成本較高。本文用三步方法合成了可回收的Fe3O4/SiO2/Bi2WO6磁性復(fù)合光催化劑,通過溶劑熱法合成具有磁性的Fe3O4,用溶膠凝膠法在Fe3O4表面覆蓋SiO2層,后將磁性顆粒與Bi2WO6納米片相結(jié)合。光催化劑的形貌結(jié)構(gòu)及性能通過XRD、SEM、PL、UV-vis進(jìn)行表征測試。結(jié)果表明,直徑約500 nm的Fe3O4微球附著在邊長約500 nm的Bi2WO6納米片的表面,SiO2在兩者之間起到了粘連作用。光催化劑Fe3O4/SiO2/Bi2WO6對于羅丹明B的光降解活性較好,且有一定磁性,可以通過外加磁場將其從溶液中分離,有較大的應(yīng)用潛力。"/>

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Fe3O4/SiO2/Bi2WO6磁性復(fù)合光催化劑的制備及其光催化性能
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浙江大學(xué)材料科學(xué)與工程學(xué)院,浙江大學(xué)材料科學(xué)與工程學(xué)院;浙江加州國際納米研究院,浙江大學(xué)材料科學(xué)與工程學(xué)院,浙江大學(xué)材料科學(xué)與工程學(xué)院,浙江大學(xué)材料科學(xué)與工程學(xué)院,浙江加州國際納米研究院

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國家高技術(shù)研究發(fā)展計劃(863計劃)(項(xiàng)目號2015AA034701)


Preparation of magnetic composite photocatalyst Fe3O4/SiO2/Bi2WO6 and its photocatalytic activity
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Department of Materials Science and Engineering of Zhejiang University,Hangzhou PR China,Department of Materials Science and Engineering of Zhejiang University,Hangzhou PR China Zhejiang-California International NanoSystems Institute;China,Department of Materials Science and Engineering of Zhejiang University,Hangzhou,Department of Materials Science and Engineering of Zhejiang University,Hangzhou PR China,Department of Materials Science and Engineering of Zhejiang University,Hangzhou PR China Zhejiang-California International NanoSystems Institute

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    摘要:

    鎢酸鉍(Bi2WO6),結(jié)構(gòu)最簡單的Aurivillius相化合物,是近期受到研究者關(guān)注的新型光催化材料。然而,光催化劑粉末在反應(yīng)介質(zhì)中難被回收,工業(yè)化應(yīng)用成本較高。本文用三步方法合成了可回收的Fe3O4/SiO2/Bi2WO6磁性復(fù)合光催化劑,通過溶劑熱法合成具有磁性的Fe3O4,用溶膠凝膠法在Fe3O4表面覆蓋SiO2層,后將磁性顆粒與Bi2WO6納米片相結(jié)合。光催化劑的形貌結(jié)構(gòu)及性能通過XRD、SEM、PL、UV-vis進(jìn)行表征測試。結(jié)果表明,直徑約500 nm的Fe3O4微球附著在邊長約500 nm的Bi2WO6納米片的表面,SiO2在兩者之間起到了粘連作用。光催化劑Fe3O4/SiO2/Bi2WO6對于羅丹明B的光降解活性較好,且有一定磁性,可以通過外加磁場將其從溶液中分離,有較大的應(yīng)用潛力。

    Abstract:

    Bismuth tungstate (Bi2WO6), one of the simplest Aurivillius phase oxides, has been used as a new photocatalyst that works under visible light irradiation. However, it is not easy to reuse the photocatalyst due to difficulty in its recovery from the reaction media. Indeed, reusability and recyclability of photocatalyst are major factors considered in industrial applications. In the paper, magnetically recoverable photocatalyst Fe3O4/SiO2/Bi2WO6 was synthesized by a three-step approach. After a hydrothermal process of preparing ferroferric oxide (Fe3O4), these Fe3O4 nanoparticles were coated with SiO2 by sol-gel method. Finally, Fe3O4/SiO2 nanoparticles were immobilized onto the surface of Bi2WO6 by a second hydrothermal process. The morphology, structure and properties of the composite were characterized by XRD, SEM, PL spectra and UV-vis absorption spectrum. The results show that the Bi2WO6 nanosheets structures with average diameters of 500nm are further decorated by Fe3O4 nanoparticles with an average diameter of 500nm. The photocatalytic activity of Fe3O4/SiO2/Bi2WO6 to degrade rhodamine B was close to that of pure Bi2WO6. The photocatalyst with appropriate superparamagnetism can be easily re-collected by applying an external magnetic field. It shows potential applications in pollutant degradation.

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巫華婷,丁新更,李文琪,任春溶,楊輝. Fe3O4/SiO2/Bi2WO6磁性復(fù)合光催化劑的制備及其光催化性能[J].稀有金屬材料與工程,2018,47(S2):199~203.[Huating Wu, Xingeng Ding, Wenqi Li, Chunrong Ren, Hui Yang. Preparation of magnetic composite photocatalyst Fe3O4/SiO2/Bi2WO6 and its photocatalytic activity[J]. Rare Metal Materials and Engineering,2018,47(S2):199~203.]
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  • 收稿日期:2017-11-28
  • 最后修改日期:2017-11-28
  • 錄用日期:2018-02-01
  • 在線發(fā)布日期: 2018-11-01
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