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燒結(jié)溫度對(duì)振蕩壓力燒結(jié)工藝制備高性能氧化鋯陶瓷的影響
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作者單位:

1.航天特種材料及工藝技術(shù)研究所;2.清華大學(xué)

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中圖分類號(hào):

TQ174

基金項(xiàng)目:

國(guó)家自然科學(xué)基金資助(項(xiàng)目號(hào)51427802,51672147)


Effect of Sintering Temperature on the Structures and Properties of High Quality Zirconia Ceramics under Oscillatory Pressure
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Affiliation:

1.Aerospace Institute of Advanced Materials &2.Processing Technology;3.State Key Laboratory of New Ceramics and Fine Processing,Tsinghua University

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    摘要:

    本文采用新型振蕩壓力燒結(jié)技術(shù)制備了高性能氧化鋯陶瓷,并系統(tǒng)研究了該工藝中燒結(jié)溫度對(duì)于氧化鋯陶瓷中致密度、晶粒尺寸、微觀結(jié)構(gòu)以及力學(xué)性能的影響關(guān)系。結(jié)果表明:振蕩壓力燒結(jié)工藝中,隨著燒結(jié)溫度的提高,氧化鋯試樣致密度變化不明顯,但晶粒尺寸在不斷增加,試樣表面均幾乎無(wú)氣孔,當(dāng)目標(biāo)溫度達(dá)到1300℃時(shí),氧化鋯陶瓷的硬度和抗彎強(qiáng)度均最大,分別為16.6GPa和1455MPa。相比常壓和熱壓燒結(jié)工藝,振蕩壓力的引入明顯降低了氧化鋯陶瓷的致密化溫度,且獲得了更高的力學(xué)強(qiáng)度和斷裂可靠性。

    Abstract:

    In this paper, oscillatory pressure sintering technique (OPS) was used to prepare high quality zirconia ceramics. The effects of sintering temperature on the density, grain size, microstructure and mechanical properties of zirconia ceramics were firstly investigated. The results show that under the application of oscillatory pressure, the variation of relative densities is not obvious while the grain sizes significantly increase during the increased sintering temperature. All specimens reached a nearly full density as there was scarcely any pores on the polished surface. The highest hardness and bending strength of 16.6 GPa and 1455 MPa, respectively, are reached when the target temperature reaches 1300°C. Compared with conventional pressureless and hot pressure sintering process, the introduction of oscillatory pressure significantly reduces the densification temperature of zirconia ceramics, and evidently enhances mechanical strength and fracture reliability.

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韓耀,李海燕,謝志鵬,王華棟,李淑琴.燒結(jié)溫度對(duì)振蕩壓力燒結(jié)工藝制備高性能氧化鋯陶瓷的影響[J].稀有金屬材料與工程,2020,49(2):639~643.[Han Yao, Li Haiyan, Xie Zhipeng, Wang Huadong, Li Shuqing. Effect of Sintering Temperature on the Structures and Properties of High Quality Zirconia Ceramics under Oscillatory Pressure[J]. Rare Metal Materials and Engineering,2020,49(2):639~643.]
DOI:10.12442/j. issn.1002-185X. QH20190048

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  • 收稿日期:2019-04-02
  • 最后修改日期:2019-05-07
  • 錄用日期:2019-10-23
  • 在線發(fā)布日期: 2020-03-12
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