3N4;CuGaO2;氣體傳感器;甲苯"/> 3N4/CuGaO2復合材料。采用XRD、SEM、TEM和XPS對制備的樣品進行了表征。研究了一系列C3N4/CuGaO2復合材料的氣敏性能。結(jié)果表明,基于C3N4/CuGaO2-0.3復合材料(C3N4與CuGaO2的摩爾比為0.3:1)的氣體傳感器對甲苯的傳感性能優(yōu)于CuGaO2傳感器。相比較于CuGaO2傳感器的工作溫度(140 ℃),C3N4/CuGaO2-0.3復合材料傳感器的最佳工作溫度僅為25 ℃,對100 μL/L甲苯氣體的響應(yīng)達到28,檢出限低至0.01 μL/L。對100 μL/L甲苯氣體的響應(yīng)時間和恢復時間分別為114.2和27.4 s。此外,用于檢測甲苯的C3N4/CuGaO2-0.3復合材料傳感器還具有優(yōu)異的長期穩(wěn)定性、良好的重復性和優(yōu)異的抗?jié)裥阅堋?/>

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水熱法制備C3N4/CuGaO2 復合物及其氣敏性能
作者:
作者單位:

1.安徽工業(yè)大學,安徽 馬鞍山 243002;2.臨沂大學,山東 臨沂 276005

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基金項目:

National Natural Science Foundation of China (61971003); National Natural Science Foundation of Shandong Province (ZR2020MF025).


Gas Sensing Properties of C3N4/CuGaO2 Composites Prepared by Hydrothermal Method
Author:
Affiliation:

1.Anhui University of Technology, Ma'anshan 243002, China;2.Linyi University, Linyi 276005, China

Fund Project:

National Natural Science Foundation of China (61971003); National Natural Science Foundation of Shandong Province (ZR2020MF025)

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    摘要:

    采用簡單水熱法合成了一系列C3N4/CuGaO2復合材料。采用XRD、SEM、TEM和XPS對制備的樣品進行了表征。研究了一系列C3N4/CuGaO2復合材料的氣敏性能。結(jié)果表明,基于C3N4/CuGaO2-0.3復合材料(C3N4與CuGaO2的摩爾比為0.3:1)的氣體傳感器對甲苯的傳感性能優(yōu)于CuGaO2傳感器。相比較于CuGaO2傳感器的工作溫度(140 ℃),C3N4/CuGaO2-0.3復合材料傳感器的最佳工作溫度僅為25 ℃,對100 μL/L甲苯氣體的響應(yīng)達到28,檢出限低至0.01 μL/L。對100 μL/L甲苯氣體的響應(yīng)時間和恢復時間分別為114.2和27.4 s。此外,用于檢測甲苯的C3N4/CuGaO2-0.3復合材料傳感器還具有優(yōu)異的長期穩(wěn)定性、良好的重復性和優(yōu)異的抗?jié)裥阅堋?/p>

    Abstract:

    A series of C3N4/CuGaO2 composites were synthesized by facile hydrothermal method. The prepared samples were characterized by XRD, SEM, TEM, and XPS. The gas sensing properties of the C3N4/CuGaO2 composites were investigated. Results demonstrate that the gas sensor based on C3N4/CuGaO2-0.3 composite (molar ratio of C3N4 to CuGaO2 is 0.3:1) shows better sensing performance to toluene than CuGaO2 sensor does. Compared with the operating temperature of CuGaO2 sensor (140 °C), the optimal working temperature of C3N4/CuGaO2-0.3 composite sensor is only 25 °C, the response to 100 μL/L toluene gas reaches 28, and the detection limit is as low as 0.01 μL/L. The response time and recovery time for the detection of 100 μL/L toluene vapor are 114.2 and 27.4 s, respectively. Moreover, the C3N4/CuGaO2-0.3 composite sensor also exhibits excellent long-term stability, good repeatability, and extraordinary humidity resistance for toluene detection.

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王春水,吳海燕,焦成,儲向峰,梁士明,何麗芳.水熱法制備C3N4/CuGaO2 復合物及其氣敏性能[J].稀有金屬材料與工程,2024,53(6):1536~1542.[Wang Chunshui, Wu Haiyan, Jiao Cheng, Chu Xiangfeng, Liang Shiming, He Lifang. Gas Sensing Properties of C3N4/CuGaO2 Composites Prepared by Hydrothermal Method[J]. Rare Metal Materials and Engineering,2024,53(6):1536~1542.]
DOI:10.12442/j. issn.1002-185X. E20230035

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  • 收稿日期:2023-09-13
  • 最后修改日期:2024-01-16
  • 錄用日期:2024-01-31
  • 在線發(fā)布日期: 2024-06-20
  • 出版日期: 2024-06-17