g/Tl+Tx/Tl+Tx/Tg(Tx為起始結(jié)晶溫度;Tl為液體溫度;Tg為玻璃化轉(zhuǎn)變溫度),并從降溫過程非晶化與晶化之間的競爭關(guān)系和準(zhǔn)則各組成項(xiàng)對準(zhǔn)則的均衡貢獻(xiàn)兩個方面進(jìn)行了修訂:G-FASm=Tg/(1.5Tx)+Tx/Tl+Tx/Tg和G-FASm′=Tg/Tl+Tx/Tl+(Tx/Tg)a (a≈1.5±0.2)。討論了G-FAS與臨界冷卻速率Rc、G-FAS與Txg(Txg反映了玻璃的過冷液區(qū),Txg=Tx/Tg)的相關(guān)性,分別能夠反映GFA和GS。通過大量金屬玻璃和其他玻璃形成體從GFA和GS兩方面對判定準(zhǔn)則的有效性進(jìn)行了評估,結(jié)果顯示:該判定準(zhǔn)則無論是GFA方面還是GS方面,在不同玻璃形成體系中均可靠有效,具有廣泛應(yīng)用性。提出的Tri-FAS和G-FAS判定準(zhǔn)則在玻璃的生產(chǎn)和實(shí)際應(yīng)用過程中具有指導(dǎo)作用。"/>

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玻璃形成能力及穩(wěn)定性三角形判定準(zhǔn)則
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國家自然科學(xué)基金項(xiàng)目(51971103);甘肅省重點(diǎn)研發(fā)計(jì)劃(20YF8GA052)


Triangle Criterion of Glass-Forming Ability and Stability for Metallic Glasses
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National Natural Science Foundation of China (51971103); Key Research and Development Program of Gansu Province (20YF8GA052)

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    摘要:

    根據(jù)降溫過程的玻璃形成能力(GFA)和升溫過程的玻璃穩(wěn)定性(GS),構(gòu)建了以偽四特征參數(shù)組合為頂點(diǎn)的判定玻璃形成能力和穩(wěn)定性的三角形(Tri-FAS),從而推導(dǎo)出判定GFA&GS的準(zhǔn)則:G-FAS=Tg/Tl+Tx/Tl+Tx/TgTx為起始結(jié)晶溫度;Tl為液體溫度;Tg為玻璃化轉(zhuǎn)變溫度),并從降溫過程非晶化與晶化之間的競爭關(guān)系和準(zhǔn)則各組成項(xiàng)對準(zhǔn)則的均衡貢獻(xiàn)兩個方面進(jìn)行了修訂:G-FASm=Tg/(1.5Tx)+Tx/Tl+Tx/Tg和G-FASm′=Tg/Tl+Tx/Tl+(Tx/Tg)a (a≈1.5±0.2)。討論了G-FAS與臨界冷卻速率Rc、G-FAS與TxgTxg反映了玻璃的過冷液區(qū),Txg=Tx/Tg)的相關(guān)性,分別能夠反映GFA和GS。通過大量金屬玻璃和其他玻璃形成體從GFA和GS兩方面對判定準(zhǔn)則的有效性進(jìn)行了評估,結(jié)果顯示:該判定準(zhǔn)則無論是GFA方面還是GS方面,在不同玻璃形成體系中均可靠有效,具有廣泛應(yīng)用性。提出的Tri-FAS和G-FAS判定準(zhǔn)則在玻璃的生產(chǎn)和實(shí)際應(yīng)用過程中具有指導(dǎo)作用。

    Abstract:

    Based on the glass-forming ability (GFA) during cooling process and the glass stability (GS) of heating process, a triangle to evaluate GFA and GS, namely Tri-FAS, with the combination of pseudo-four characteristic parameters as vertices was established. Accordingly, a GFA&GA criterion (G-FAS) was deduced as G-FAS=Tg/Tl+Tx/Tl+Tx/Tg (Tx is onset crystallization temperature; Tl is liquid temperature; Tg is glass transition temperature). Additionally, the criterion was modified based on the competitive relationship between amorphous phase and crystal phase during cooling process and the contribution of each component to the criterion: G-FASm=Tg/(1.5Tx)+Tx/Tl+Tx/Tg and G-FASm′=Tg/Tl+Tx/Tl+(Tx/Tg)a (a≈1.5±0.2). The correlation between G-FAS and critical cooling rate Rc and that between G-FAS and Txg (Txg reflects the supercooled liquid region of glass, Txg=Tx/Tg) were discussed, which could reflect GFA and GS, respectively. Through the determination results of GFA and GS of abundant metallic glasses and other glass formers, the validity of the proposed G-FAS criterion was evaluated. Results show that with respect to both GFA and GS, the G-FAS criterion is reliable in various glass former systems, showing wide applications. The proposed Tri-FAS and G-FAS criterion can provide guidance during the fabrication and application of metallic glasses.

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李曉誠,寇生中,趙燕春,李春燕,李春玲.玻璃形成能力及穩(wěn)定性三角形判定準(zhǔn)則[J].稀有金屬材料與工程,2024,53(1):31~37.[Li Xiaocheng, Kou Shengzhong, Zhao Yanchun, Li Chunyan, Li Chunling. Triangle Criterion of Glass-Forming Ability and Stability for Metallic Glasses[J]. Rare Metal Materials and Engineering,2024,53(1):31~37.]
DOI:10.12442/j. issn.1002-185X. E20230034

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  • 收稿日期:2023-09-12
  • 最后修改日期:2023-09-20
  • 錄用日期:2023-10-07
  • 在線發(fā)布日期: 2023-11-16
  • 出版日期: 2024-01-24