2.1Sr1.96Ca1-xNaxCu2.0O8+d超導(dǎo)材料。Bi-2212前驅(qū)體粉末采用改進(jìn)的共沉淀工藝制備,并在燒結(jié)前將前驅(qū)體粉末與NaOH混合。本文系統(tǒng)研究了Na離子摻雜對Bi-2212體系晶格結(jié)構(gòu)、相組成、微結(jié)構(gòu)和相關(guān)超導(dǎo)性能的影響。Na離子摻雜導(dǎo)致Bi-2212體系相轉(zhuǎn)變溫度的顯著降低。因此在SPS過程中,燒結(jié)溫度相應(yīng)發(fā)生了變化。但Na摻雜仍然導(dǎo)致大量Bi2Sr2CuO6 (Bi-2201)相生成,進(jìn)而導(dǎo)致了超導(dǎo)相含量的降低和織構(gòu)度的破壞,所以給體系的超導(dǎo)電性帶來了負(fù)面的影響。另一方面,Na摻雜相Bi-2212中摻入了大量的點(diǎn)缺陷,這些點(diǎn)缺陷可以作為有效釘扎中心。因此,通過優(yōu)化Na摻雜Bi-2212的燒結(jié)工藝,有可能在高場條件下獲得體系性能的改善。"/>

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Na摻雜對Bi-2212高溫超導(dǎo)體性能影響研究
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西北有色金屬研究院超導(dǎo)材料研究所

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基金項(xiàng)目:

國家自然基金面上項(xiàng)目No.51472206,聚變堆項(xiàng)目No.2013GB110001,國家重點(diǎn)研發(fā)計(jì)劃No.2017YFB0902303


Influences of Na doping on the superconducting properties of Bi-2212 High temperature superconductors
Author:
Affiliation:

1.Superconducting Materials Research Center,Northwest Institute for Nonferrous Metal Research,Xi’an;2.Western Superconducting Technologies Co,Ltd,Xi’an;3.College of Materials Science and Engineering,Xi’an University of Technology,Xi’an

Fund Project:

National Science Foundation of China under contract No. 51472206, the National ITER program of China under contract No. 2013GB110001, and National Key Research and Development Program 2017YFB0902303

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    摘要:

    本文采用放電等離子燒結(jié)(SPS)工藝制備了Na摻雜的Bi2.1Sr1.96Ca1-xNaxCu2.0O8+d超導(dǎo)材料。Bi-2212前驅(qū)體粉末采用改進(jìn)的共沉淀工藝制備,并在燒結(jié)前將前驅(qū)體粉末與NaOH混合。本文系統(tǒng)研究了Na離子摻雜對Bi-2212體系晶格結(jié)構(gòu)、相組成、微結(jié)構(gòu)和相關(guān)超導(dǎo)性能的影響。Na離子摻雜導(dǎo)致Bi-2212體系相轉(zhuǎn)變溫度的顯著降低。因此在SPS過程中,燒結(jié)溫度相應(yīng)發(fā)生了變化。但Na摻雜仍然導(dǎo)致大量Bi2Sr2CuO6 (Bi-2201)相生成,進(jìn)而導(dǎo)致了超導(dǎo)相含量的降低和織構(gòu)度的破壞,所以給體系的超導(dǎo)電性帶來了負(fù)面的影響。另一方面,Na摻雜相Bi-2212中摻入了大量的點(diǎn)缺陷,這些點(diǎn)缺陷可以作為有效釘扎中心。因此,通過優(yōu)化Na摻雜Bi-2212的燒結(jié)工藝,有可能在高場條件下獲得體系性能的改善。

    Abstract:

    Polycrystalline bulks Bi2.1Sr1.96Ca1-xNaxCu2.0O8+d (Bi-2212) with Na doping content of x=0, 0.02, 0.05 and 0.10 were fabricated by spark plasma sintering (SPS) process. The Bi-2212 precursor powders were synthesized by modified co-precipitation process, and NaOH powders were added into as dopants before calcination. The influences of Na+ ions doping on the lattice parameters, phase composition, microstructures as well as related superconducting properties were systematically investigated. The introduction of Na in Bi-2212 system could cause an obvious decrease of phase transition temperatures. Thus during the SPS process, although the sintering temperature has been greatly decreased accordingly, Na doped Bi-2212 bulks still tended to decomposed into Bi2Sr2CuO6 (Bi-2201) phase, which led to the decrease of both superconducting phase content and texture degrees, and thus caused negative effects on superconducting properties. On the other hand, Na doping introduced more point defects into Bi-2212 matrix, which acted as flux pinning centers during current transport process, and contributed to the increase of current capacity under high field. Therefore, Na doping with optimized sintering parameters should be considered as a promising method for the enhancement of high field current capacity in Bi-2212 system.

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張勝楠,馬小波,崔利軍,黃英健,李成山,馮建情,閆果,張平祥. Na摻雜對Bi-2212高溫超導(dǎo)體性能影響研究[J].稀有金屬材料與工程,2020,49(4):1184~1190.[Shengnan Zhang, Xiaobo Ma, Lijun Cui, Yingjian Huang, Chegnshan Li, Jianqing Feng, Guo yan, Pingxiang Zhang. Influences of Na doping on the superconducting properties of Bi-2212 High temperature superconductors[J]. Rare Metal Materials and Engineering,2020,49(4):1184~1190.]
DOI:10.12442/j. issn.1002-185X. E20180037

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  • 收稿日期:2018-11-21
  • 最后修改日期:2019-01-14
  • 錄用日期:2019-02-21
  • 在線發(fā)布日期: 2020-05-07
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