1相。AlTiCrNiCu低密度高熵合金具有高的壓縮性能,其屈服強(qiáng)度和抗壓強(qiáng)度分別為約840MPa和約960MPa。該研究結(jié)果為非球形金屬粉末的BJ3DP打印成形-燒結(jié)提供了思路及參考依據(jù),進(jìn)一步拓展了金屬粉末BJ3DP打印成形的應(yīng)用范圍。"/>

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機(jī)械合金化制備AlTiCrNiCu低密度高熵合金的BJ3DP及其燒結(jié)致密化研究
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華南理工大學(xué) 廣東省金屬新材料制備與成形重點(diǎn)實(shí)驗(yàn)室

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廣東省自然科學(xué)基金(2018A030313486);江西省重點(diǎn)研發(fā)計(jì)劃項(xiàng)目(20171ACH80012)


Research on BJ3DP and sintering densification of AlTiCrNiCu low-density high entropy alloy prepared by mechanical alloying
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1.Guangdong Provincial Key Laboratory for Processing and Forming of Advanced Merallic Materials,South China University of Technology;2.China

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Sintering densification mechanism of AlSiTi series high entropy alloys based on binder jetting 3D printing method

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    摘要:

    粘結(jié)劑噴射3D打印(BJ3DP)工藝是當(dāng)前的研究熱點(diǎn)。通常,粉末床打印工藝需要球形粉末,這限制了一些熔點(diǎn)差較大的高熵合金粉末的制備以及打印成形。本研究主要針對(duì)非球形顆粒的BJ3DP打印-燒結(jié)行為開展研究。結(jié)果表明,采用機(jī)械合金化法制備了BCC結(jié)構(gòu)的近球形AlTiCrNiCu低密度高熵合金粉末,其粒徑分布為6.72~67.52μm,平均粒徑為21.17μm,滿足BJ3DP打印工藝要求。正交實(shí)驗(yàn)結(jié)果表明,當(dāng)粘結(jié)劑飽和度60%、層厚120μm和鋪粉速度15pps時(shí),BJ3DP打印的生坯致密度最高(約44.7%)。生坯經(jīng)過1190℃/4h燒結(jié)后,其塊體的致密度達(dá)到91.6%。AlTiCrNiCu低密度高熵合金為多相結(jié)構(gòu),基體為B2相,還包括BCC、FCC和少量L21相。AlTiCrNiCu低密度高熵合金具有高的壓縮性能,其屈服強(qiáng)度和抗壓強(qiáng)度分別為約840MPa和約960MPa。該研究結(jié)果為非球形金屬粉末的BJ3DP打印成形-燒結(jié)提供了思路及參考依據(jù),進(jìn)一步拓展了金屬粉末BJ3DP打印成形的應(yīng)用范圍。

    Abstract:

    The binder jetting 3D printing (BJ3DP) process is currently a research hotspot. Generally, the powder bed printing process requires spherical powders, which limits the preparation and printing of some HEA powders with large melting point differences. This study mainly focuses on the BJ3DP printing-sintering behavior of non-spherical particles. The results showed that the near-spherical AlTiCrNiCu low-density HEA powder with BCC structure was prepared by mechanical alloying, with a particle size ranged from 6.72 to 67.52 μm and an average particle size of 21.17 μm, which met the requirements of the BJ3DP printing process. The results of the orthogonal experiment indicate that when the binder saturation is 60%, the layer thickness is 120 μm, and the powder feeding speed is 15 pps, the green density of BJ3DP printing is the highest (about 44.7%). After sintering at 1190℃ for 4 hours, the density of the green body reaches 91.6%. The AlTiCrNiCu low-density HEA has a multiphase structure, with the B2 phase as the matrix, including BCC, FCC, and a small amount of L21 phase. The AlTiCrNiCu low-density HEA has high compressive properties, with a yield strength and compressive strength of approximately 840 MPa and 960 MPa, respectively. The research results provide ideas and reference for the BJ3DP printing and sintering of non-spherical metal powders, further expanding the application scope of metal powder BJ3DP printing and forming.

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朱德智,陳海鵬,蔡良福.機(jī)械合金化制備AlTiCrNiCu低密度高熵合金的BJ3DP及其燒結(jié)致密化研究[J].稀有金屬材料與工程,,().[Zhu Dezhi, Chen Haipeng, Cai Liangfu. Research on BJ3DP and sintering densification of AlTiCrNiCu low-density high entropy alloy prepared by mechanical alloying[J]. Rare Metal Materials and Engineering,,().]
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  • 收稿日期:2024-09-30
  • 最后修改日期:2025-02-14
  • 錄用日期:2025-02-21
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