2+的移動(dòng)障礙,最終提高鎂離子電池CuS正極材料的充放電性能。"/>

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納米花狀CuS作為鎂離子電池正極材料
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1.重慶大學(xué) 材料科學(xué)與工程學(xué)院 國家鎂合金材料工程技術(shù)研究中心,重慶 400044;2.重慶大學(xué) 機(jī)械傳動(dòng)國家重點(diǎn)實(shí)驗(yàn)室,重慶 400044;3.池州市質(zhì)量監(jiān)督檢驗(yàn)研究院,安徽 池州 247100

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國家自然科學(xué)基金項(xiàng)目(面上項(xiàng)目,重點(diǎn)項(xiàng)目,重大項(xiàng)目)


Nanoflower Copper Sulfide as Cathode Materials for Magnesium Ion Batteries
Author:
Affiliation:

1.National Engineering Research Center for Magnesium Alloys, College of Materials Science and Engineering, Chongqing University, Chongqing 400044, China;2.State Key Laboratory of Mechanical Transmission for Advance Equipment, Chongqing University, Chongqing 400044, China;3.Chizhou Research Institute of Quality Supervision and Inspection, Chizhou 247100, China

Fund Project:

National Natural Science Foundation of China (52171101); Fundamental Research Funds for the Central Universities (2024IAIS-QN009); National Key R&D Program of China (2021YFB3701100)

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    摘要:

    在水熱合成過程中加入表面活性劑十六烷基三甲基溴化銨(CTAB),調(diào)節(jié)乙二醇的用量為50vol%,合成了鎂離子電池正極材料CuS-C50。結(jié)果表明:CuS-C50具有完整的納米花狀結(jié)構(gòu),在氯化鋁-季戊四醇四甲醚/四氫呋喃(APC/THF)電解液中,當(dāng)電流密度為50 mA/g時(shí),其比容量高達(dá)331.19 mAh/g;當(dāng)電流密度為200 mA/g時(shí),其比容量在50次循環(huán)后仍保持136.92 mAh/g。形貌表征結(jié)果表明,完整的納米花狀結(jié)構(gòu)可以提供更多的活性位點(diǎn),減少M(fèi)g2+的移動(dòng)障礙,最終提高鎂離子電池CuS正極材料的充放電性能。

    Abstract:

    CuS-C50, the cathode materials for magnesium ion batteries, was synthesized by adding the surfactant cetyltrimethyl ammonium bromide (CTAB) and adjusting the percentage of ethylene glycol to 50vol% in hydrothermal synthesis process. Results show that CuS-C50 has the complete nanoflower structure. In aluminum chloride-pentamethylcydopentodiene/tetrahydrofuran (APC/THF) electrolyte, the CuS-C50 exhibits a high specific capacity of 331.19 mAh/g when the current density is 50 mA/g and still keeps a specific capacity of 136.92 mAh/g over 50 cycles when the current density is 200 mA/g. Results of morphology characterizations indicate that the complete nanoflower structure can provide more active sites and reduce the barriers for Mg2+ movement, eventually improving the charge and discharge performance of the CuS cathode materials for magnesium ion batteries.

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何元泰,吳量,史永安,鐘志永,姚文輝,潘復(fù)生.納米花狀CuS作為鎂離子電池正極材料[J].稀有金屬材料與工程,2025,54(3):545~553.[He Yuantai, Wu Liang, Shi Yongan, Zhong Zhiyong, Yao Wenhui, Pan Fusheng. Nanoflower Copper Sulfide as Cathode Materials for Magnesium Ion Batteries[J]. Rare Metal Materials and Engineering,2025,54(3):545~553.]
DOI:10.12442/j. issn.1002-185X.20240361

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  • 收稿日期:2024-06-17
  • 最后修改日期:2024-10-14
  • 錄用日期:2024-10-18
  • 在線發(fā)布日期: 2025-03-25
  • 出版日期: 2025-03-25