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難成形生坯用石蠟的改性及其在WC-Co硬質(zhì)合金中的應(yīng)用
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1.西北工業(yè)大學(xué) 材料學(xué)院,陜西 西安 710072;2.江蘇泰爾新材料股份有限公司,江蘇 蘇州 410075

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Modification of Paraffin Wax for Manufacturing Difficult-to-Form Green Compacts and Its Application in WC-Co Ce-mented Carbides
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1.School of Materials Science and Engineering, Northwestern Polytechnical University, Xi'an710072, China;2.Jiangsu Taier Novel Material Co., Ltd, Suzhou410075, China

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    摘要:

    工業(yè)模壓生產(chǎn)深井字形WC-Co硬質(zhì)合金塊是一個難以解決的技術(shù)難題,主要是所用石蠟基成形劑不合適造成的。采用有機高分子樹脂、增塑劑、表面活性劑和潤滑劑這4種改性劑對成形劑石蠟做了改性,研究了樹脂種類的定性篩選和4種石蠟改性劑組合的正交實驗,以得到改性劑的優(yōu)化定量比例。結(jié)果表明,樹脂中小分子插入石蠟支晶間隙可能是樹脂和石蠟相容性提高的一個重要原因。通過正交實驗,確定了成型劑的最佳配方為:100份58#石蠟、15份EVA-2、4份DPHP、4份油酸酰胺和2份硬脂酸。該優(yōu)化配方在一家中國公司的工業(yè)生產(chǎn)中得到了應(yīng)用,生產(chǎn)出了質(zhì)量合格的深井形狀硬質(zhì)合金產(chǎn)品,其中WC質(zhì)量分數(shù)為90%,Co質(zhì)量分數(shù)為10%。

    Abstract:

    The production of deep well-shaped WC-Co cemented carbide blocks via industrial powder pressing remains a challenging technical problem, primarily due to the unsuitability of the forming agent. The forming agent paraffin wax was modified through four types of modifiers, including organic high-molecular-mass resins, plasticizers, surfactants and lubricants. The qualitative screening of resin types was explored and an orthogonal experiment involving the combination of these four paraffin wax modifiers was conducted to obtain an optimized quantitative ratio of modifiers. The results reveal that the insertion of the small molecule chain of resin into the interstitial spaces of paraffin wax crystals is likely a crucial factor for improving the compatibility between the resin and paraffin wax. Through orthogonal experiments, the optimized formulation for the forming agent is determined: 100 parts of 58# paraffin wax, 15 parts of EVA-2, 4 parts of DPHP, 4 parts of oleic acid amide and 2 parts of stearic acid. This optimized formulation is applied to industrial production at one Chinese company, and qualified deep well-shaped cemented carbide products are achieved, which contain 90wt% WC and 10wt% Co.

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李毅,王錦程,倪娟,沈少波.難成形生坯用石蠟的改性及其在WC-Co硬質(zhì)合金中的應(yīng)用[J].稀有金屬材料與工程,2024,53(11):3064~3076.[Li Yi, Wang Jincheng, Ni Juan, Shen Shaobo. Modification of Paraffin Wax for Manufacturing Difficult-to-Form Green Compacts and Its Application in WC-Co Ce-mented Carbides[J]. Rare Metal Materials and Engineering,2024,53(11):3064~3076.]
DOI:10.12442/j. issn.1002-185X.20240163

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歷史
  • 收稿日期:2024-03-21
  • 最后修改日期:2024-10-12
  • 錄用日期:2024-05-08
  • 在線發(fā)布日期: 2024-11-18
  • 出版日期: 2024-11-08