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Cr含量的Ni-Cr合金激光熔覆層組織與耐磨性能
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華北電力大學(xué) 電站能量傳遞轉(zhuǎn)化與系統(tǒng)教育部重點(diǎn)實(shí)驗(yàn)室,北京 102206

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General Fund Project in Equipment Pre-research Field (61409220202)


Microstructure and Wear Resistance of Ni-Cr Alloy Laser Cladding Layer with High Cr Content
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Key Laboratory of Power Station Energy Transfer Conversion and System, Ministry of Education, North China Electric Power University, Beijing 102206, China

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General Fund Project in Equipment Pre-research Field (61409220202)

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    摘要:

    采用高速激光熔覆技術(shù)制備了4種Ni-xCr合金熔覆層(x=20、40、60和80,質(zhì)量分?jǐn)?shù)),研究了不同Cr含量的Ni-Cr合金熔覆層的顯微組織與耐磨性能的關(guān)系。結(jié)果表明,4種Ni-Cr合金熔覆層的組織均為網(wǎng)狀枝晶結(jié)構(gòu)。其中,Ni-20Cr和Ni-40Cr為單相的 γ-(Ni, Cr)固溶體,其磨損機(jī)制為粘著磨損和磨粒磨損。隨著Cr含量的增加,Ni-60Cr和Ni-80Cr為γ-(Ni, Cr)相和Cr相,且存在富Cr沉淀物,磨損機(jī)制為粘著磨損、磨粒磨損和疲勞磨損。適度增加Cr含量可以提高Ni-Cr合金熔覆層的硬度和耐磨性。然而,過量添加Cr會(huì)導(dǎo)致富Cr沉淀物的析出。這些沉淀物的硬度為2430.4 MPa,低于Ni-60Cr基體(4024.86 MPa)和Ni-80Cr基體(7022.68 MPa)的硬度。富Cr沉淀物與熔覆層基體之間存在硬度過渡區(qū),裂紋極易在過渡區(qū)萌生并擴(kuò)展,造成深層剝落,不利于熔覆層的耐磨性能。Ni-80Cr的硬度最高,但其Cr含量過高導(dǎo)致表面存在大量的貫穿性裂紋和較多的富Cr沉淀物,最終表現(xiàn)出最差的耐磨性能。Ni-60Cr擁有較高硬度和致密的微觀結(jié)構(gòu),因此表現(xiàn)出最好的耐磨性能。

    Abstract:

    Four kinds of Ni-xCr alloy laser cladding layers (x=20, 40, 60 and 80, wt%) were prepared by high-speed laser cladding technique, and the relationship between microstructure and wear resistance of Ni-Cr alloy laser cladding layers with different Cr contents was investigated. The results show that the four Ni-Cr alloy laser cladding layers all have reticulated dendritic structures. Among them, Ni-20Cr and Ni-40Cr are single-phase γ-(Ni, Cr) solid solutions, and their wear mechanisms are adhesive wear and abrasive wear. With the increase in Cr content, Ni-60Cr and Ni-80Cr are γ-(Ni, Cr) phase and Cr phase, as well as Cr-rich precipitates, and their wear mechanisms are adhesive wear, abrasive wear and fatigue wear. A moderate increase in Cr content can enhance the hardness and wear resistance of Ni-Cr alloy laser cladding layer. However, excessive addition of Cr results in the precipitation of Cr-rich precipitates. The hardness of these precipitates is 2430.4 MPa, which is lower than the hardness of the Ni-60Cr matrix (4024.86 MPa) and Ni-80Cr matrix (7022.68 MPa). A hardness transition zone exists between the Cr-rich precipitates and the matrix. Cracks are likely to initiate and expand in this zone, leading to deep spalling, which is not conducive to the wear-resistant properties of the laser cladding layer. Ni-80Cr has the highest hardness, but its high Cr content leads to a large number of penetrating cracks and Cr-rich precipitates on the surface, ultimately resulting in the worst wear resistance. Ni-60Cr exhibits the best wear resistance due to its high hardness and dense microstructure.

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潘朝陽,劉宗德,申越,路鑫杰,毛潔,王鑫宇,李家璇.高Cr含量的Ni-Cr合金激光熔覆層組織與耐磨性能[J].稀有金屬材料與工程,2024,53(9):2438~2445.[Pan Chaoyang, Liu Zongde, Shen Yue, Lu Xinjie, Mao Jie, Wang Xinyu, Li Jiaxuan. Microstructure and Wear Resistance of Ni-Cr Alloy Laser Cladding Layer with High Cr Content[J]. Rare Metal Materials and Engineering,2024,53(9):2438~2445.]
DOI:10.12442/j. issn.1002-185X.20230814

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  • 收稿日期:2023-12-16
  • 最后修改日期:2024-03-19
  • 錄用日期:2024-03-22
  • 在線發(fā)布日期: 2024-09-12
  • 出版日期: 2024-09-04