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球磨和液相燒結(jié)制備W-Ni-Fe合金的組織和力學(xué)性能
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作者單位:

1.天津大學(xué) 材料科學(xué)與工程學(xué)院,天津 300072;2.安泰天龍鎢鉬科技有限公司,北京 100094;3.海天塑機(jī)集團(tuán)有限公司,浙江 寧波 315801

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基金項(xiàng)目:

the National Key R&D Program of China (2023YFB12002), National Natural Science Foundation of China (Grant No. U22A20172 and 52171044)


Microstructure and Properties of 93W-4.6Ni-2.4Fe Prepared by Ball-Milling and Liquid Phase Sintering
Author:
Affiliation:

1.School of Materials Science and Engineering, Tianjin University, Tianjin 300072, China;2.ATTL Advanced Materials Co., Ltd, Beijing 100094, China;3.Haitian Plastics Machinery Group Co., Ltd, Ningbo 315801, China

Fund Project:

National Key R&D Program of China (2023YFB3712002); National Natural Science Foundation of China (U22A20172, 52171044)

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    摘要:

    為了制備出優(yōu)異、經(jīng)濟(jì)友好的鎢重合金,在1450~1510 ℃的燒結(jié)溫度范圍內(nèi),通過球磨和液相燒結(jié)制備了93W-4.6Ni-2.4Fe(質(zhì)量分?jǐn)?shù))合金。進(jìn)一步研究了試樣的微觀結(jié)構(gòu)和斷裂模式。結(jié)果表明,在不同燒結(jié)溫度下,燒結(jié)的試樣表現(xiàn)出相似的兩相顯微結(jié)構(gòu)和韌性斷裂模式。隨著燒結(jié)溫度的升高,鎢顆粒尺寸也逐漸增大。當(dāng)燒結(jié)溫度達(dá)到或超過1480 ℃時(shí),合金相對(duì)密度達(dá)到99.0%以上。1480 ℃燒結(jié)時(shí)可獲得具有最佳抗拉伸強(qiáng)度(940 MPa)和延伸率(32.6%)組合的試樣。在1480 ℃下燒結(jié)的試樣具有優(yōu)異的延展性,這與γ相的網(wǎng)絡(luò)結(jié)構(gòu)、韌窩的均勻分布以及兩相的協(xié)同作用有關(guān)。試樣的高強(qiáng)度歸因于細(xì)化的鎢顆粒尺寸和球形的鎢顆粒。

    Abstract:

    In order to produce economical tungsten alloys with superior mechanical properties, 93W-4.6Ni-2.4Fe (wt%) tungsten heavy alloys were fabricated by ball milling and liquid phase sintering at a temperature range of 1450?1510 °C. The microstructure and the fracture modes of the specimens were examined. Results show that the specimens sintered at different temperatures display similar dual-phase microstructure and ductile fracture modes. With the increase in sintering temperature, the tungsten particle size also gradually grows. At the temperatures above 1480 °C, the relative density reaches above 99.0%. The optimal sintering temperature of the specimen with the best tensile strength (940 MPa) and elongation (32.6%) combination is determined to be 1480 °C. The excellent ductility of the specimen sintered at 1480 °C is associated with the network structure of γ phase, the uniform distribution of dimples and the synergistic effect of these two phases. The high strength of the specimen is attributed to the refined tungsten particle size and the spherical tungsten particles.

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引用本文

王姿曈,董帝,熊寧,徐嘉偉,董智,馬宗青.球磨和液相燒結(jié)制備W-Ni-Fe合金的組織和力學(xué)性能[J].稀有金屬材料與工程,2024,53(5):1229~1235.[Wang Zitong, Dong Di, Xiong Ning, Xu Jiawei, Dong Zhi, Ma Zongqing. Microstructure and Properties of 93W-4.6Ni-2.4Fe Prepared by Ball-Milling and Liquid Phase Sintering[J]. Rare Metal Materials and Engineering,2024,53(5):1229~1235.]
DOI:10.12442/j. issn.1002-185X.20230778

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  • 收稿日期:2023-12-01
  • 最后修改日期:2024-02-19
  • 錄用日期:2024-02-26
  • 在線發(fā)布日期: 2024-05-27
  • 出版日期: 2024-05-22