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CrZrCuW/CuCr整體材料界面組織與性能的影響
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西安理工大學,陜西 西安 710048

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中圖分類號:

TB331

基金項目:

國家自然科學基金(52274366)


Effects of Cr and Zr on Interface Microstructures and Properties of CuW/CuCr Integral Materials
Author:
Affiliation:

Xi'an University of Technology, Xi'an 710048, China

Fund Project:

國家自然基金重點項目(52274366)

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    摘要:

    采用整體燒結熔滲法制備了含Cu-Cr-Zr粉末夾層的CuW/CuCr整體材料,研究了Cr和Zr含量、固溶時效熱處理對界面及兩側材料組織與性能的影響。結果表明,隨著Cu-15%Cr-x%Zr(質量分數(shù))夾層中Zr含量的增加,整體材料CuCr側共晶相增多,CuCr端導電率有所下降;硬度呈先升高后降低的變化趨勢。同時Zr元素的添加促進了Cr元素向W中擴散。制備了含不同成分夾層的整體材料拉伸試棒,測試其界面抗拉強度并分析了斷口形貌。發(fā)現(xiàn)夾層中Zr含量在0.5%時,整體材料界面抗拉強度達到最大值517 MPa,與未添加Zr的含Cu-15%Cr夾層的CuW/CuCr整體材料相比提高了18%,拉伸斷口中Cu相撕裂棱變淺變短,W顆粒發(fā)生解理斷裂的數(shù)量增多,表明Cu/W相界面和CuCr端強度均得到了提高。

    Abstract:

    CuW/CuCr integral materials with Cu-Cr-Zr powder interlayer was prepared by integral sintering infiltration method. The effects of Cr and Zr content and solution aging heat treatment on the microstructure and properties of the interface and both sides of the material were studied. The results show that with the increase in Zr content in Cu-15%Cr-x%Zr (mass fraction, similarly hereinafter) interlayer, the eutectic phase amount on CuCr side of the integral material increases, and the conductivity at CuCr end decreases. The hardness increases first and then decreases. At the same time, the addition of Zr promotes the diffusion of Cr into W. The tensile test bars of integral materials with different interlayers were prepared, and the interfacial tensile strength was tested and the fracture morphology was analyzed. It is found that when the Zr content in the interlayer is 0.5%, the interfacial tensile strength of the whole material reaches the maximum value of 517 MPa, which is 18% higher than that of the CuW/CuCr integral material with Cu-15%Cr interlayer without Zr. The tearing edge of Cu phase in the tensile fracture becomes shallower and shorter, and the number of cleavage fractures of W particles increases, which indicates that the interfacial strength of Cu/W phase and the end strength of CuCr are improved.

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楊曉紅,劉子賢,李雪健,肖鵬,梁淑華.CrZrCuW/CuCr整體材料界面組織與性能的影響[J].稀有金屬材料與工程,2025,54(3):774~780.[Yang Xiaohong, Liu Zixian, Li Xuejian, Xiao Peng, Liang Shuhua. Effects of Cr and Zr on Interface Microstructures and Properties of CuW/CuCr Integral Materials[J]. Rare Metal Materials and Engineering,2025,54(3):774~780.]
DOI:10.12442/j. issn.1002-185X.20230737

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  • 收稿日期:2023-11-17
  • 最后修改日期:2024-02-01
  • 錄用日期:2024-02-28
  • 在線發(fā)布日期: 2025-03-25
  • 出版日期: 2025-03-25