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CsCl對NaCl-KCl-CsCl熔鹽物理性質(zhì)及鈮涂層電沉積行為的影響
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國防科技大學(xué)

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中圖分類號:

TG146.4+16

基金項(xiàng)目:

湖南省青年人才支持計(jì)劃


Effect of CsCl on the physical properties of NaCl-KCl-CsCl molten salts and electrodeposition behavior of niobium coatings
Author:
Affiliation:

National University of Defense Technology

Fund Project:

the Support Program for Young Talents of Hunan

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    摘要:

    因其優(yōu)異的綜合理化性能,鈮(Nb)被廣泛應(yīng)用于航空航天、核能和超導(dǎo)領(lǐng)域。其涂層制備方法中,熔鹽電沉積技術(shù)沉積速率快、陰極電流效率高、繞鍍性好,有望實(shí)現(xiàn)大規(guī)模工業(yè)化生產(chǎn)和應(yīng)用。當(dāng)前廣泛使用的氟化物支持電解質(zhì)體系毒性大、環(huán)保性差,亟待開展更環(huán)保的全氯化物支持電解質(zhì)體系的開發(fā)工作。為實(shí)現(xiàn)支持電解質(zhì)熔鹽物性的調(diào)控和絡(luò)合離子的穩(wěn)定化,本文在NaCl-KCl體系中添加CsCl,制備全氯化物支持電解質(zhì)體系,研究CsCl對支持電解質(zhì)熔鹽物理性質(zhì)及Nb涂層電沉積行為的影響。結(jié)果表明,NaCl-KCl-CsCl三元混合熔鹽的共晶溫度約為485℃,隨CsCl含量增加,熔鹽的初晶溫度先降低后增大,密度增大,電導(dǎo)率和表面張力減小。CsCl通過改變?nèi)埯}的初晶溫度和電導(dǎo)率影響熔鹽中離子的傳質(zhì)速度,進(jìn)而影響電沉積Nb涂層的表面質(zhì)量,其優(yōu)選含量約為60wt.%。CsCl的添加可使熔鹽中含氧絡(luò)合離子NbOF63-的還原電位負(fù)于NbF72-,有助于獲得不含氧雜質(zhì)的Nb涂層。

    Abstract:

    Niobium (Nb) is widely used in aerospace, nuclear energy and superconducting fields, due to its excellent comprehensive physical and chemical properties. In the preparation methods of the Nb coating, the molten salt electrodeposition technology has fast deposition rate, high cathode current efficiency and is suitable for complex shape components, which is expected to realize large-scale industrialized production and application. Since the current widely used fluoride-supported electrolyte system is highly toxic and environmentally unfavorable, there is an urgent need to carry out the development of a more environmentally friendly all chloride supporting electrolyte system. To achieve the regulation of the molten salt’s physical properties of the supporting electrolyte and the stabilization of the complexing ions, this study adds CsCl to the NaCl-KCl system to prepare an all chloride supporting electrolyte system and investigates the effect of CsCl on the molten salt’s physical properties of the supporting electrolyte and the electrodeposition behavior of the Nb coating. The results showed that the eutectic temperature of the NaCl-KCl-CsCl ternary mixed molten salt was about 485 °C. With the increase of CsCl content, the initial crystallization temperature of molten salt decreased at first and then increased, the density increased, and the conductivity and surface tension decreased. CsCl affected the mass transfer rate of ions in molten salt by changing the initial crystal temperature and conductivity of molten salt, and then affected the surface quality of electrodeposited Nb coating, and its preferred content was about 60 wt.%. The addition of CsCl can make the reduction potential of the oxygen-containing complex ion NbOF63- in the molten salt negative to that of NbF72-, which was helpful to obtain Nb coatings without oxygen impurities.

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引用本文

朱利安,袁偉超,胡雙鵬,王震,葉益聰,白書欣. CsCl對NaCl-KCl-CsCl熔鹽物理性質(zhì)及鈮涂層電沉積行為的影響[J].稀有金屬材料與工程,2024,53(5):1332~1342.[Zhu Lian, Yuan Weichao, Hu Shuangpeng, Wang Zhen, Ye Yicong, Bai Shuxin. Effect of CsCl on the physical properties of NaCl-KCl-CsCl molten salts and electrodeposition behavior of niobium coatings[J]. Rare Metal Materials and Engineering,2024,53(5):1332~1342.]
DOI:10.12442/j. issn.1002-185X.20230682

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  • 收稿日期:2023-11-01
  • 最后修改日期:2023-12-25
  • 錄用日期:2024-01-05
  • 在線發(fā)布日期: 2024-05-28
  • 出版日期: 2024-05-22