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雙硅酸鹽高熵材料熱穩(wěn)定性研究
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中國民航大學

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中圖分類號:

TG148

基金項目:

中央高校基本業(yè)務經(jīng)費資助項目(3122019189)


Study on Thermal Stability of Bisilicate High Entropy Materials
Author:
Affiliation:

Civil Aviation University of China

Fund Project:

Funding Program for Basic Operating Funds for Central Universities (3122019189)

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    摘要:

    通過固相反應制備了Yb2Si2O7和高熵雙硅酸鹽粉末(Yb0.25Y0.25Lu0.25Er0.25)2Si2O7、(Yb0.2Y0.2Lu0.2Er0.2Sc0.2)2Si2O7、(Yb0.2Y0.2Lu0.2Er0.2Ho0.2)2Si2O7,對原始和保溫處理后四種陶瓷塊體的物相組成、熱膨脹系數(shù)、熱導率和彈性模量進行分析。結(jié)果表明:高熵(Yb0.25Y0.25Lu0.25Er0.25)2Si2O7的熱膨脹系數(shù)和熱導率與Yb2Si2O7相似,彈性模量降低了10.28%;(Yb0.2Y0.2Lu0.2Er0.2Sc0.2)2Si2O7與(Yb0.25Y0.25Lu0.25Er0.25)2Si2O7相比熱膨脹系數(shù)、熱導率和彈性模量分別降低了5.59%、15.51%和18.74%;與(Yb0.25Y0.25Lu0.25Er0.25)2Si2O7相比(Yb0.2Y0.2Lu0.2Er0.2Ho0.2)2Si2O7的熱膨脹系數(shù)升高了14.24%,熱導率和彈性模量下降了26.35%和24.78%。這表明添加了Ho元素的(Yb0.2Y0.2Lu0.2Er0.2Ho0.2)2Si2O7熱導率下降最大,熱膨脹系數(shù)增加后與基底CMC的熱膨脹系數(shù)更為接近。在1200 ℃和1300 ℃保溫10 h、30 h、50 h后,Yb2Si2O7、(Yb0.25Y0.25Lu0.25Er0.25)2Si2O7、(Yb0.2Y0.2Lu0.2Er0.2Sc0.2)2Si2O7和(Yb0.2Y0.2Lu0.2Er0.2Ho0.2)2Si2O7均表現(xiàn)出良好的高溫相穩(wěn)定性,其熱膨脹系數(shù)下降,但依然與基底CMC的熱膨脹系數(shù)相接近,它們的彈性模量隨著保溫時長的增加而增加。

    Abstract:

    Yb2Si2O7 and high entropy double silicate powders (Yb0.25Y0.25Lu0.25Er0.25)2Si2O7, (Yb0.2Y0.2Lu0.2Er0.2Sc0.2)2Si2O7, and (Yb0.2Y0.2Lu0.2Er0.2Ho0.2)2Si2O7 were prepared through solid-state reaction. The phase composition, thermal expansion coefficient, thermal conductivity, and elastic modulus of their ceramic blocks and insulation treatment were studied. The results show that due to the addition of rare earth elements Y, Lu, and Er, the thermal expansion coefficient and thermal conductivity of high entropy (Yb0.25Y0.25Lu0.25Er0.25)2Si2O7 are similar to those of Yb2Si2O7, but the elastic modulus decreases the least, at 10.28%; Due to the addition of Scelements, high entropy (Yb0.2Y0.2Lu0.2Er0.2Sc0.2)2Si2O7 has lower thermal expansion coefficient and thermal conductivity compared to (Yb0.25Y0.25Lu0.25Er0.25)2Si2O7, and the elastic modulus is reduced by 18.74%; Compared with (Yb0.25Y0.25Lu0.25Er0.25)2Si2O7, the high entropy (Yb0.2Y0.2Lu0.2Er0.2Ho0.2)2Si2O7 doped with Ho element has a higher thermal expansion coefficient and lower thermal conductivity, but its elastic modulus decreases the most, reaching 24.78%. After insulation at 1200 ℃ and 1300 ℃ for 10, 30, and 50 hours, Yb2Si2O7, (Yb0.25Y0.25Lu0.25Er0.25)2Si2O7, (Yb0.2Y0.2Lu0.2Er0.2Sc0.2)2Si2O7, and (Yb0.2Y0.2Lu0.2Er0.2Ho0.2)2Si2O7 all exhibited good high-temperature stability, and their elastic modulus increased with the increase of insulation time, while their thermal expansion coefficient gradually decreased. After high entropy double silicate insulation treatment, it still exhibits good high-temperature phase stability and has a similar coefficient of thermal expansion to the substrate, indicating that the prepared high entropy double silicate is suitable for thermal environment barrier coating materials of high thrust weight ratio aviation engines.

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丁坤英.雙硅酸鹽高熵材料熱穩(wěn)定性研究[J].稀有金屬材料與工程,2024,53(10):2968~2974.[Ding Kunying. Study on Thermal Stability of Bisilicate High Entropy Materials[J]. Rare Metal Materials and Engineering,2024,53(10):2968~2974.]
DOI:10.12442/j. issn.1002-185X.20230680

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  • 收稿日期:2023-10-30
  • 最后修改日期:2023-12-15
  • 錄用日期:2024-01-05
  • 在線發(fā)布日期: 2024-10-17
  • 出版日期: 2024-09-27