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不同鎳基粉末高溫合金的氧化行為研究
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作者單位:

1.中南大學 粉末冶金國家重點實驗室;2.深圳市萬澤中南研究院有限公司;3.深圳市萬澤航空科技有限責任公司;4.中國人民解放軍93145部隊,廣東 深圳

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通訊作者:

中圖分類號:

TG132.3+

基金項目:

廣東省引進創(chuàng)新創(chuàng)業(yè)團隊項目(607264877417);深圳市工業(yè)和信息化局項目(201806071114243770)


Oxidation Behavior of Different Powder Metallurgy Nickel Based Superalloys
Author:
Affiliation:

1.State Key Laboratory of Powder Metallurgy,Central South University;2.Shenzhen Wedge Central South Research Institute Co., Ltd.;3.Shenzhen Wedge Aviation Technology Co Ltd;4.Unit 93145 of the Chinese People''s Liberation Army

Fund Project:

Guangdong Innovative and Entrepreneurial Research Team Program(607264877417);Industry and Information Technology Bureau of Shenzhen Municipality ( 201806071114243770)

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    摘要:

    對FGH4113A(WZ-A3)、FGH96和FGH97三種鎳基粉末高溫合金進行815、900和1000℃大氣環(huán)境下的高溫氧化試驗。采用靜態(tài)增重法測定合金在不同溫度下的氧化動力學曲線并評估其抗氧化能,利用X射線衍射、掃描電子顯微鏡、能譜儀等分析合金氧化后的表面及截面形貌、成分及結構等。結果表明:815和900℃時三種合金均為完全抗氧化級,1000℃時WZ-A3為抗氧化級,F(xiàn)GH96為次抗氧化級,F(xiàn)GH97仍為完全抗氧化級。WZ-A3和FGH96合金經(jīng)1000℃高溫氧化后氧化層結構類似,最外層為TiO2,中間層為Cr2O3+少量TiO2的混合層,最內(nèi)層為樹枝狀Al2O3;WZ-A3合金氧化中間層和最內(nèi)層的分界處還存在Nb和Mo元素的富集。三種合金氧化性能的差別與Al含量有關。FGH97中Al含量較高,經(jīng)1000℃氧化后,外表面存在孤島狀TiO2,在表面形成致密的Al2O3層,有效阻隔了其他合金元素向外擴散,使合金表現(xiàn)出優(yōu)異的抗氧化性。WZ-A3和FGH96中Al含量較低,形成的樹枝狀Al2O3層無法有效形成隔離保護,形成的Cr2O3氧化層在高溫下?lián)]發(fā)形成孔洞破壞了氧化層的致密度。1.0wt% Ta和 1.2wt%Nb的添加一定程度提高了WZ-A3合金的抗氧化性。

    Abstract:

    Three nickel-based powder superalloys FGH4113A (WZ-A3), FGH96 and FGH97 were subjected to oxidation tests in air at 815, 900 and 1000℃. Static weight gain method was used to determine the oxidation dynamics curve of the alloys at different temperatures and to evaluate the oxidation resistance. The surface and cross-sectional morphology, composition and structure of specimens were analyzed after oxidation tests by X-ray diffraction, scanning electron microscopy, energy spectrometer. The results showed that the three alloys were completely antioxidant grade at 815 and 900℃, WZ-A3, FGH96 and FGH97 were antioxidant grade, secondary antioxidant grade and complete antioxidant grade respectively at 1000℃.The oxide layers of WZ-A3 and FGH96 alloys were similar after oxidation at a high temperature of 1000℃, which consisted of an outermost layer TiO2, a middle layer mixed layer of Cr2O3 and a small amount of TiO2, an innermost layer was dendritic Al2O3. There was the enrichment of Nb and Mo elements at the boundary between the middle and the innermost layer for WZ-A3. The difference in oxidation properties of the three alloys was related to Al content. Al content was low in WZ-A3 and FGH96 and the dendritic Al2O3 layer formed can’t effectively form isolation. After the Cr2O3 reaction, it evaporated to form holes, which destroys the density of the oxide layer at high temperatures. Al content in FGH97 was high such that the formation of a dense Al2O3 layer on the surface can effectively block the outward diffusion of other alloying elements after oxidation at 1000℃, so the FGH97 exhibited excellent oxidation resistance. The addition of 1.0wt%Ta and 1.2wt%Nb has improved the oxidation resistance of WZ-A3 alloy to a certain extent.

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熊江英,尹超,鄒志歡,伍靖,楊金龍,霍紅光.不同鎳基粉末高溫合金的氧化行為研究[J].稀有金屬材料與工程,2024,53(12):3475~3484.[Xiong Jiangying, Yin Chao, Zou Zhihuan, Wu Jing, Yang Jinlong, Huo Hongguang. Oxidation Behavior of Different Powder Metallurgy Nickel Based Superalloys[J]. Rare Metal Materials and Engineering,2024,53(12):3475~3484.]
DOI:10.12442/j. issn.1002-185X.20230656

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  • 收稿日期:2023-10-20
  • 最后修改日期:2023-12-26
  • 錄用日期:2024-01-05
  • 在線發(fā)布日期: 2024-12-23
  • 出版日期: 2024-12-16