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溫度場作用下Fe-Cr合金中空洞演化與遷移的相場模擬
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1.中國核動(dòng)力研究設(shè)計(jì)院第一研究所;2.西北工業(yè)大學(xué)凝固技術(shù)國家重點(diǎn)實(shí)驗(yàn)室;3.西安理工大學(xué)材料學(xué)院

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國家自然科學(xué)基金項(xiàng)目(面上項(xiàng)目,重點(diǎn)項(xiàng)目,重大項(xiàng)目),陜西省自然科學(xué)基礎(chǔ)研究計(jì)劃項(xiàng)目


A phase field study of voids
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西安理工大學(xué)

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    摘要:

    堆芯關(guān)鍵部件材料Fe-Cr基奧氏體鋼在高溫和輻照環(huán)境下長時(shí)服役,輻照空位簇聚形成空洞導(dǎo)致輻照腫脹和硬化現(xiàn)象。本文采用相場方法耦合中心溫度場和一維溫度場研究Fe-Cr合金空位簇聚和空洞演化行為。計(jì)算結(jié)果表明,中心溫度場下,溫度梯度促使空位向中心溫度高的區(qū)域遷移,導(dǎo)致中心高溫區(qū)域空洞濃度高,優(yōu)先出現(xiàn)空洞形核,空洞尺寸大,低溫區(qū)域空位濃度低,空洞尺寸?。灰痪S溫度場下,體擴(kuò)散機(jī)制控制下,空洞的遷移速度與溫度梯度正相關(guān),與初始孔徑無關(guān);表面擴(kuò)散機(jī)制控制下,空洞的遷移速度與溫度梯度成正相關(guān),與初始孔徑負(fù)相關(guān)。該研究結(jié)果啟發(fā)局域組織老化引起的導(dǎo)熱不均材料或宏觀溫度梯度下服役部件的組織和性能預(yù)測。

    Abstract:

    The austenite Fe-Cr steels used as the critical in-pile components because of its good high temperature resistance, corrosion resistance and excellent mechanical properties and thermal strength, bear long-period high temperatures and irradiation; the irradiated vacancies aggregate into voids leading to irradiation swelling and hardening, which seriously affects the service safety of the reactor. The phase field method coupling temperature field is employed by solving the phase field equations based the Fourier spectrum method to investigate the voids behavior of austenite Fe-Cr steels upon a central and a one-dimensional temperature field. As the temperature goes down from the center radically in a central temperature field, the vacancies diffuse toward the high-temperature center region driven by the temperature gradient, resulting in the instability of the double voids model, and gradually dissolves to form a new void in the high temperature center region. In the central temperature field, the voids nucleate earlier and grow faster with a sizeable scale in the high temperature than that in the lower temperature region due to the higher vacancy concentration in the central high temperature region. Based on the force-flow relation in the principle of irreversible thermodynamics, the migration behavior of voids upon a one-dimensional temperature gradient is studied by adding advection term to the phase field evolution equation Cahn-Hilliard equation. It has been observed in the experiments that the size of voids in irradiated austenite Fe-Cr steel is nanoscale, and it is generally believed that the nanoscale voids migration is controlled by the bulk diffusion mechanism and surface diffusion mechanism. Therefore, the effects of temperature gradient and initial size of voids on the voids migration upon a one-dimensional temperature gradient in austenite Fe-Cr steel are studied considering both the bulk diffusion mechanism and surface diffusion mechanism respectively. The migration rate governed by the bulk diffusion mechanism positively depends on the temperature gradients but not the initial void"s size. The migration rate governed by the surface diffusion mechanism positively depends on the temperature gradients but is negatively related to the initial void"s size. At the same time, in the process of migration, the shape of the void will also change, and the void will be elongated along the direction of temperature gradient, and the front end is sharper along the direction of temperature gradient, and the back end is wider. The studies inspire the microstructure aging and properties prediction caused by inhomogeneous heat conduct or macroscopic uneven temperature distribution.

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朱偉,程大釗,劉彩艷,馬聰,吳璐,張靜.溫度場作用下Fe-Cr合金中空洞演化與遷移的相場模擬[J].稀有金屬材料與工程,2024,53(8):2193~2199.[Zhu Wei, Cheng Dazhao, Liu Caiyan, Ma Cong, Wu lu, Zhang Jing. A phase field study of voids[J]. Rare Metal Materials and Engineering,2024,53(8):2193~2199.]
DOI:10.12442/j. issn.1002-185X.20230621

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  • 收稿日期:2023-10-08
  • 最后修改日期:2023-11-06
  • 錄用日期:2023-11-13
  • 在線發(fā)布日期: 2024-08-20
  • 出版日期: 2024-08-08