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Bi-2212/Ag多芯線材中孔洞的形成研究
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西北有色金屬研究院

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國家自然科學基金(項目號:52277029)、陜西省自然科學基礎研究計劃(項目編號:2020JM-650)


Study on Bubbles Formation of Bi-2212/Ag Multifilament Wires
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1.Northwest Institute for Nonferrous Metal Research,Xi’an 710016;2.China

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    摘要:

    采用粉末裝管法制備了多芯Bi2Sr2CaCu2Ox(Bi-2212)線材,在一個標準大氣壓、氧氣氣氛條件下對兩端封閉和兩端開口的線材進行熱處理,制備了不同熔化-淬火態(tài)及晶化生長后的樣品。系統(tǒng)研究了線材內(nèi)部氣體含量對線材直徑、微觀形貌以及超導相形成的影響。結(jié)果表明:純氧氣氛下燒結(jié)的線材芯絲內(nèi)部殘留大量孔洞,大尺寸孔洞形成于線材熔化階段,并會部分保留到最終線材內(nèi)部。氣體壓力促使熔化的液相進入Ag層填充缺陷,導致芯絲之間熔連合并,造成線材織構(gòu)下降。

    Abstract:

    The Bi2Sr2CaCu2Ox(Bi-2212) multifilament round wires were fabricated by the powder-in-tube technique. Open ends and closed ends wires were heat-treated in 1atm flowing O2. Several samples at various points of the partial-melt processing were prepared. The influences of the gas content inside wires on the diameters, microstructures and the phase compositions were systematically investigated. The results showed that large amount of bubbles were residual during the partial melting process of Bi-2212 filaments in pure O2 atmosphere. Porosity agglonerated large bubbles on melting of the Bi-2212 powders. These bubbles were partially retained inside the final wires. High internal gas pressure would cause the molten phase towards the Ag layer to fill the defects, resulting the filament-to-filament bonding and the worse texture.

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徐曉燕,郝清濱,焦高峰,姚凱,劉國慶. Bi-2212/Ag多芯線材中孔洞的形成研究[J].稀有金屬材料與工程,2024,53(11):3241~3245.[XU Xiaoyan, Hao Qingbin, Jiao Gaofeng, Yao Kai, Liu Guoqing. Study on Bubbles Formation of Bi-2212/Ag Multifilament Wires[J]. Rare Metal Materials and Engineering,2024,53(11):3241~3245.]
DOI:10.12442/j. issn.1002-185X.20230617

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  • 收稿日期:2023-10-06
  • 最后修改日期:2023-12-25
  • 錄用日期:2024-01-05
  • 在線發(fā)布日期: 2024-11-20
  • 出版日期: 2024-11-08