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金屬鈾在氧氣、水汽及含氧水汽中腐蝕的動力學(xué)與機(jī)理研究現(xiàn)狀
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表面物理與化學(xué)重點(diǎn)實驗室

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中國工程物理研究院基金資助(項目號:YZJJZQ2022012、YZJJZL2023106)和國家自然科學(xué)基金資助(項目號22073084)


Research progress on the corrosion kinetics and mechanism of uranium metal in oxygen, water vapor and oxygenated water vapor
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Science and Technology on Surface Physics and Chemistry Laboratory

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    摘要:

    金屬鈾是一種重要的戰(zhàn)略核材料,在能源系統(tǒng)和國防工業(yè)中廣泛應(yīng)用。然而,金屬鈾在使役中極易被環(huán)境氣氛快速腐蝕,不僅會產(chǎn)生放射性腐蝕產(chǎn)物還會對使用性能和壽命帶來嚴(yán)重威脅。雖然金屬鈾的腐蝕相關(guān)研究已持續(xù)開展了數(shù)十年,但由于金屬鈾具有放射性、腐蝕速率快、腐蝕產(chǎn)物種類多等原因,導(dǎo)致目前對金屬鈾的腐蝕行為認(rèn)識還不夠清楚。本文基于金屬鈾在氧氣、水汽和含氧水汽中的腐蝕行為的相關(guān)研究,簡介了金屬鈾的典型腐蝕產(chǎn)物,從腐蝕動力學(xué)模型、腐蝕速率方程和活化能方面梳理了金屬鈾的腐蝕動力學(xué)研究現(xiàn)狀,從腐蝕介質(zhì)的解離擴(kuò)散、以及關(guān)鍵中間腐蝕產(chǎn)物演化等方面綜述了金屬鈾的腐蝕機(jī)理研究進(jìn)展,總結(jié)了目前較為清晰和統(tǒng)一的認(rèn)識,指出了當(dāng)前該研究領(lǐng)域中仍存在的爭議性問題,展望了未來的主要研究方向,為金屬鈾的腐蝕評估、壽命預(yù)測和腐蝕防護(hù)提供研究基礎(chǔ)。

    Abstract:

    Uranium is an important strategic nuclear material, widely used in energy systems and defense industries. However, uranium is easily corroded quickly by the environmental atmosphere in service, which not only produces radioactive corrosion products but also poses a serious threat to service performance and life. Although research on the corrosion of uranium has been carried out for decades, the understanding of the corrosion behavior of uranium is not clear because of its radioactivity, fast corrosion rate, and various corrosion products. Based on the relevant research on the corrosion behavior of uranium in oxygen, water vapor, and oxygen-containing water vapor, this paper briefly introduces the typical corrosion products of uranium, and reviews the current research status of uranium corrosion kinetics from the aspects of corrosion kinetics model, corrosion rate equation and activation energy. This paper reviews the research progress on the corrosion mechanism of uranium from the aspects of the dissociation diffusion of corrosive media and the evolution of key intermediate corrosion products, summarizes the current clear and unified understanding, points out the current controversial issues in the research field, and looks forward to the main research directions in the future, providing research basis for the corrosion assessment, life prediction and corrosion protection of uranium.

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陳廣,丁茜,張廣豐,李海波,李贛.金屬鈾在氧氣、水汽及含氧水汽中腐蝕的動力學(xué)與機(jī)理研究現(xiàn)狀[J].稀有金屬材料與工程,2024,53(12):3553~3568.[Chen Guang, Ding Qian, Zhang Guangfeng, Li Haibo, Li Gan. Research progress on the corrosion kinetics and mechanism of uranium metal in oxygen, water vapor and oxygenated water vapor[J]. Rare Metal Materials and Engineering,2024,53(12):3553~3568.]
DOI:10.12442/j. issn.1002-185X.20230604

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  • 收稿日期:2023-09-26
  • 最后修改日期:2024-09-16
  • 錄用日期:2024-09-20
  • 在線發(fā)布日期: 2024-12-23
  • 出版日期: 2024-12-16