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PtCo合金電催化劑在燃料電池氧還原催化中的研究現(xiàn)狀與進展
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云南貴金屬實驗室有限公司 稀貴金屬綜合利用新技術(shù)國家重點實驗室

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中圖分類號:

O643.36

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云南省基礎(chǔ)研究專項-重點項目(202101AS070049);云南省基礎(chǔ)研究專項——重點研發(fā)計劃(YPML-2023050215);云南貴金屬實驗室科技計劃項目(YPML-2022050232);云南省貴金屬新材料控股集團有限公司R D項目(2020040602)


Current Status and Progress of PtCo Alloy Electrocatalysts in Fuel Cell Oxygen Reduction Reaction Catalysis
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Yunnan Precious Metals Laboratory Co.,LTD,State Key Laboratory of Advanced Technologies for Comprehensive Utilization of Platinum Metals

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    摘要:

    質(zhì)子交換膜燃料電池(PEMFC)具有高效、低溫、環(huán)保等優(yōu)點,是解決能源短缺和環(huán)境污染雙重問題的潛在方案。然而,其陰極氧還原反應(yīng)(ORR)中遲緩的動力學(xué)過程不得不依賴稀缺昂貴的Pt基催化劑,這阻礙了PEMFC技術(shù)的進一步發(fā)展和應(yīng)用。為了降低成本并保證高效的催化性能,近年來研究人員已開發(fā)了多種技術(shù)策略,通過引入過渡金屬與Pt合金化為主要策略之一,特別是PtCo雙金屬催化劑,它表現(xiàn)了更優(yōu)異的ORR催化性能。本文綜述了PtCo合金催化劑在PEMFC氧還原催化中的最新進展和現(xiàn)狀,首先總結(jié)了催化劑組分控制、粒徑調(diào)控、晶面調(diào)控、摻雜等調(diào)控策略對燃料電池催化活性的影響,其次詳細介紹了最有前途的PtCo合金結(jié)構(gòu),如多面體、核殼、納米框架、有序金屬間結(jié)構(gòu)等PtCo合金催化劑,并對催化劑載體研究進行了討論,最后指出了PtCo合金催化劑在其應(yīng)用中存在的挑戰(zhàn)以及未來前景。

    Abstract:

    Proton exchange membrane fuel cells (PEMFCs) are potential solutions for the dual problems of energy shortage and environmental pollution, due to their high efficiency, low temperature, and eco-friendliness. However, the slow kinetic process in its cathodic oxygen reduction reaction (ORR) has to rely on scarce and expensive Pt-based catalysts, which hinders the further development and application of PEMFC technology. In order to reduce the cost and ensure efficient catalytic performance, researchers have developed various technological strategies in recent years, and alloying with Pt through the introduction of transition metals is one of the main strategies, especially PtCo bimetallic catalysts, which exhibit superior ORR catalytic performance. This paper reviews the research results and current status of PtCo alloy catalysts for PEMFCs in recent years. Firstly, it summarizes the effects of modulation strategies such as catalyst component control, particle size modulation, crystal surface modulation, and doping on the catalytic activity of fuel cells. Then, it introduces the most promising PtCo alloy structures, such as polyhedral, core-shells, nano-frames, and ordered intermetallic structure, etc. It also discusses the research on catalyst supports. Finally, it identifies the existing challenges and future prospects of PtCo alloy catalysts for their applications.

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李鴻鵬,皮曉琳,倪文若,田乙然,童應(yīng)成,袁藤瑞,張振強. PtCo合金電催化劑在燃料電池氧還原催化中的研究現(xiàn)狀與進展[J].稀有金屬材料與工程,2024,53(10):2987~3000.[Li Hongpeng, Pi Xiaolin, Ni Wenruo, Tian Yiran, Tong Yingcheng, Yuan Tengrui, Zhang Zhenqiang. Current Status and Progress of PtCo Alloy Electrocatalysts in Fuel Cell Oxygen Reduction Reaction Catalysis[J]. Rare Metal Materials and Engineering,2024,53(10):2987~3000.]
DOI:10.12442/j. issn.1002-185X.20230518

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  • 收稿日期:2023-08-22
  • 最后修改日期:2023-12-12
  • 錄用日期:2024-01-05
  • 在線發(fā)布日期: 2024-10-17
  • 出版日期: 2024-09-27