10.25TiNb0.25/α-Fe合金;Fe含量;熔體快淬;微觀組織;磁性能"/> 10.25TiNb0.25/Xwt.%α-Fe永磁合金的影響。合金鑄錠均是由α-Fe相、1:12相和富Nd相組成,Fe含量增加,α-Fe相含量增加,1:12相含量減少。合金薄帶晶粒尺寸隨著Fe含量的增加而逐漸減小,并產(chǎn)生Fe2Ti相,Fe2Ti相和富 Nd 相含量隨著Fe含量的增加而逐漸減少。當(dāng)X≥15時(shí),合金薄帶只有1:12相和α-Fe相,平均晶粒尺寸減小到60 nm以下。滲氮后平均晶粒尺寸減小15%~20%,磁性能得到明顯改善。X=15時(shí),得到的氮化合金薄帶磁性能較佳,矯頑力為1010 Oe,飽和磁化強(qiáng)度為130.7 emu/g,比X=0時(shí)矯頑力提高了25%,飽和磁化強(qiáng)度提高了12%。粘結(jié)后最大磁能積先下降后升高,X=15時(shí)最高,達(dá)到了4.03 MGOe,相比于X=0時(shí)的2.88 MGOe,增幅達(dá)到了40%。X=15時(shí)的氮化合金薄帶高溫結(jié)構(gòu)穩(wěn)定性較好,在360℃以下保持結(jié)構(gòu)穩(wěn)定,高溫應(yīng)用潛力大。"/>

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Fe含量對(duì)NdFe10.25TiNb0.25N/α-Fe永磁合金微觀組織與磁性能的影響
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華北理工大學(xué) 冶金與能源學(xué)院

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TM273

基金項(xiàng)目:

國(guó)家自然科學(xué)基金資助(項(xiàng)目號(hào)51974134);河北省科技重大專項(xiàng)項(xiàng)目(項(xiàng)目號(hào)21281008Z)


Effect of Fe content on microstructure and magnetic properties ofNdFe10.25TiNb0.25N/α-Fe permanent magnet alloy
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College of Metallurgy and Energy North China University of Science and Technology

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    摘要:

    從微觀組織和磁性能方面研究了Fe含量對(duì)NdFe10.25TiNb0.25/Xwt.%α-Fe永磁合金的影響。合金鑄錠均是由α-Fe相、1:12相和富Nd相組成,Fe含量增加,α-Fe相含量增加,1:12相含量減少。合金薄帶晶粒尺寸隨著Fe含量的增加而逐漸減小,并產(chǎn)生Fe2Ti相,Fe2Ti相和富 Nd 相含量隨著Fe含量的增加而逐漸減少。當(dāng)X≥15時(shí),合金薄帶只有1:12相和α-Fe相,平均晶粒尺寸減小到60 nm以下。滲氮后平均晶粒尺寸減小15%~20%,磁性能得到明顯改善。X=15時(shí),得到的氮化合金薄帶磁性能較佳,矯頑力為1010 Oe,飽和磁化強(qiáng)度為130.7 emu/g,比X=0時(shí)矯頑力提高了25%,飽和磁化強(qiáng)度提高了12%。粘結(jié)后最大磁能積先下降后升高,X=15時(shí)最高,達(dá)到了4.03 MGOe,相比于X=0時(shí)的2.88 MGOe,增幅達(dá)到了40%。X=15時(shí)的氮化合金薄帶高溫結(jié)構(gòu)穩(wěn)定性較好,在360℃以下保持結(jié)構(gòu)穩(wěn)定,高溫應(yīng)用潛力大。

    Abstract:

    The effect of Fe content on NdFe10.25TiNb0.25/Xwt.%α-Fe permanent magnet alloy was studied in terms of microstructure and magnetic properties. Alloy ingot is composed of α-Fe phase, 1:12 phase and Nd-rich phase, Fe content increases, α-Fe phase content increases, and 1:12 phase content decreases. The grain size of the thin strip decreases gradually with the increase of Fe content, and Fe2Ti phase is produced. The contents of Fe2Ti phase and Nd-rich phase decrease gradually with the increase of Fe content. When X≥15, the thin strip only has 1:12 phase and a-Fe phase, and the average grain size is reduced to less than 60 nm. After nitriding, the average grain size is reduced by 15%-20%, and the magnetic properties are obviously improved. When X=15, the obtained nitrided alloy thin strip has better magnetic properties, coercivity is 1010 Oe, saturation magnetization is 130.7 emu/g, which is 25% higher than that when X=0, and saturation magnetization is 12% higher. After bonding, the maximum magnetic energy product decreases first and then increases, and reaches the highest value at X=15, reaching 4.03 MGOe, which increases by 40% compared with 2.88 MGOe at X=0. The nitriding alloy thin strip at X=15 has good structural stability at high temperature, and maintains structural stability below 360℃, which has great application potential at high temperature.

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朱子建,張穎隆,弭弘堯,馮運(yùn)莉. Fe含量對(duì)NdFe10.25TiNb0.25N/α-Fe永磁合金微觀組織與磁性能的影響[J].稀有金屬材料與工程,2024,53(9):2596~2603.[Zhu Zijian, Zhang Yinglong, Mi Hongyao, Feng Yunli. Effect of Fe content on microstructure and magnetic properties ofNdFe10.25TiNb0.25N/α-Fe permanent magnet alloy[J]. Rare Metal Materials and Engineering,2024,53(9):2596~2603.]
DOI:10.12442/j. issn.1002-185X.20230467

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  • 收稿日期:2023-07-28
  • 最后修改日期:2023-08-31
  • 錄用日期:2023-09-14
  • 在線發(fā)布日期: 2024-09-13
  • 出版日期: 2024-09-04