-離子侵蝕作用下,Al-Cu-Li合金構(gòu)件表面易出現(xiàn)點(diǎn)蝕、晶間腐蝕和剝落腐蝕現(xiàn)象。Al-Cu-Li合金的局部腐蝕主要?dú)w因于合金相與合金基體間存在電勢(shì)差,進(jìn)而導(dǎo)致在腐蝕介質(zhì)中形成微型腐蝕原電池。綜述了Al-Cu-Li合金在NaCl溶液中的腐蝕行為以及熱處理工藝對(duì)合金耐腐蝕性能的影響,重點(diǎn)分析了粗大第二相顆粒和時(shí)效析出相對(duì)Al-Cu-Li合金腐蝕性能的影響,研究了典型第3代Al-Cu-Li(2A97-T3、2A97-T6、2060-T8和2099-T83)合金以及航空用常規(guī)高強(qiáng)鋁合金2024-T4在3種不同濃度NaCl溶液中的侵蝕行為以及在質(zhì)量分?jǐn)?shù)3.5%NaCl溶液中的電化學(xué)行為。綜合分析各試樣的微觀腐蝕形貌、腐蝕電化學(xué)參數(shù)以及腐蝕程度,最終得出各試樣的耐腐蝕性能由強(qiáng)至弱為:2A97-T3>2A97-T6>2024-T4>2060-T8>2099-T83。最后揭示了Al-Cu-Li合金在腐蝕介質(zhì)中的腐蝕機(jī)理,總結(jié)了在海洋環(huán)境下鋁合金的防腐措施。本文為后續(xù)Al-Cu-Li合金防腐性能的發(fā)展和飛機(jī)耐腐蝕性能的提升提供了參考。"/>

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Al-Cu-Li合金在鹽溶液中的腐蝕行為以及腐蝕機(jī)理研究進(jìn)展
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作者單位:

1.安徽工業(yè)大學(xué) 機(jī)械工程學(xué)院,安徽 馬鞍山 243032;2.中國機(jī)械科學(xué)研究總院集團(tuán)有限公司,北京 100044;3.北京機(jī)科國創(chuàng)輕量化科學(xué)研究院有限公司 先進(jìn)成形技術(shù)與裝備國家重點(diǎn)實(shí)驗(yàn)室,北京 100083;4.北京科技大學(xué) 機(jī)械工程學(xué)院,北京 100083

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基金項(xiàng)目:

安徽省高??茖W(xué)研究項(xiàng)目(KJ2021A036)


Research Progress on Corrosion Behavior and Corrosion Mechanism of Al-Cu-Li Alloy in Sodium Chloride Solution
Author:
Affiliation:

1.School of Mechanical Engineering, Anhui University of Technology, Ma'anshan 243032, China;2.China Academy of Machinery Science and Technology Group Co., Ltd, Beijing 100044, China;3.State Key Laboratory for Advanced Forming Technology and Equipment, Beijing National Innovation Institute of Lightweight Co., Ltd, Beijing 100083, China;4.School of Mechanical Engineering, University of Science and Technology Bejing, Beijing 10083, China

Fund Project:

Major Natural Science Research Project of Anhui Provincial Department of Education (KJ2021A036); Top Talent Project of China Mechanical Science Research Institute Group Co., Ltd

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    摘要:

    Al-Cu-Li合金是航天航空工業(yè)中重要的輕質(zhì)結(jié)構(gòu)材料,已成為國產(chǎn)大飛機(jī)結(jié)構(gòu)件的關(guān)鍵材料之一。飛行器在海洋等潮濕環(huán)境服役時(shí),易受到具有腐蝕性的鹵化物陰離子的侵蝕,尤其是在Cl-離子侵蝕作用下,Al-Cu-Li合金構(gòu)件表面易出現(xiàn)點(diǎn)蝕、晶間腐蝕和剝落腐蝕現(xiàn)象。Al-Cu-Li合金的局部腐蝕主要?dú)w因于合金相與合金基體間存在電勢(shì)差,進(jìn)而導(dǎo)致在腐蝕介質(zhì)中形成微型腐蝕原電池。綜述了Al-Cu-Li合金在NaCl溶液中的腐蝕行為以及熱處理工藝對(duì)合金耐腐蝕性能的影響,重點(diǎn)分析了粗大第二相顆粒和時(shí)效析出相對(duì)Al-Cu-Li合金腐蝕性能的影響,研究了典型第3代Al-Cu-Li(2A97-T3、2A97-T6、2060-T8和2099-T83)合金以及航空用常規(guī)高強(qiáng)鋁合金2024-T4在3種不同濃度NaCl溶液中的侵蝕行為以及在質(zhì)量分?jǐn)?shù)3.5%NaCl溶液中的電化學(xué)行為。綜合分析各試樣的微觀腐蝕形貌、腐蝕電化學(xué)參數(shù)以及腐蝕程度,最終得出各試樣的耐腐蝕性能由強(qiáng)至弱為:2A97-T3>2A97-T6>2024-T4>2060-T8>2099-T83。最后揭示了Al-Cu-Li合金在腐蝕介質(zhì)中的腐蝕機(jī)理,總結(jié)了在海洋環(huán)境下鋁合金的防腐措施。本文為后續(xù)Al-Cu-Li合金防腐性能的發(fā)展和飛機(jī)耐腐蝕性能的提升提供了參考。

    Abstract:

    Al-Cu-Li alloy is a critical lightweight structural material in aviation and aerospace industry, which has become one of the key materials to manufacture the large aircraft structures in China. When the aircraft is in service in humid environments such as the ocean, it is vulnerable to be eroded by corrosive halide anions, and especially under the Cl- ion erosion, its surface of Al-Cu-Li alloy components is prone to pitting corrosion, intergranular corrosion and exfoliation corrosion. The local corrosion of Al-Cu-Li alloy is mainly attributed to the potential difference between the alloy phase and the alloy matrix, which leads to the formation of micro-corrosion battery in the corrosive medium. The corrosion behavior of Al-Cu-Li alloy in NaCl solution and the effect of heat treatment on the corrosion resistance of the alloy were reviewed. The effects of coarse second phase particles and aging precipitates on the corrosion properties of Al-Cu-Li alloy were analyzed. In addition, the corrosion behavior in NaCl solution of different contents and electrochemical behavior in 3.5wt% NaCl solution of typical third generation Al-Cu-Li (2A97-T3, 2A97-T6, 2060-T8 and 2099-T83) alloys and conventional high strength aluminum alloy 2024-T4 used in aviation were studied in NaCl solution. The micro-corrosion morphology, corrosion electrochemical parameters and corrosion degree of each sample were analyzed. Finally, the corrosion resistance of each sample was obtained, from strong to weak in an order of: 2A97-T3>2A97-T6>2024-T4>2060-T8>2099-T83. Finally, the corrosion mechanism of Al-Cu-Li alloy in a corrosive medium was revealed, and the anti-corrosion measures of aluminum alloys in marine environments were summarized. This reseach progress provides reference for the subsequent development of the Al-Cu-Li alloy corrosion protection process and the enhancement in the corrosion resistance of aircraft in humid environments.

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張鵬,包磊,饒思賢,吳進(jìn)軍,李永兵,熊成悅,孫朝陽.Al-Cu-Li合金在鹽溶液中的腐蝕行為以及腐蝕機(jī)理研究進(jìn)展[J].稀有金屬材料與工程,2023,52(12):4099~4116.[Zhang Peng, Bao Lei, Rao Sixian, Wu Jinjun, Li Yongbing, Xiong Chengyue, Sun Chaoyang. Research Progress on Corrosion Behavior and Corrosion Mechanism of Al-Cu-Li Alloy in Sodium Chloride Solution[J]. Rare Metal Materials and Engineering,2023,52(12):4099~4116.]
DOI:10.12442/j. issn.1002-185X.20230363

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  • 收稿日期:2023-06-08
  • 最后修改日期:2023-07-03
  • 錄用日期:2023-07-28
  • 在線發(fā)布日期: 2023-12-25
  • 出版日期: 2023-12-22