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雙金屬氧化物摻雜對(duì)CDPF老化性能的影響
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作者單位:

1.同濟(jì)大學(xué)汽車學(xué)院;2.北京市生態(tài)環(huán)境監(jiān)測中心

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基金項(xiàng)目:

國家自然科學(xué)基金資助(項(xiàng)目號(hào)52206167),中央高?;究蒲袠I(yè)務(wù)費(fèi)專項(xiàng)資金資助


Effect of bimetal oxide doping on the aging performance of catalyzed DPF
Author:
Affiliation:

1.School of Automotive Studies,Tongji University;2.Beijing Municipal Ecological and Environmental Monitoring Center

Fund Project:

National Natural Science Foundation of China (Project No. 52206167), Fundamental Research Funds for the Central Universities

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    摘要:

    本文基于XRD、XPS、H2-TPR等理化特性表征方法與催化劑活性評(píng)價(jià)方法,研究了摻雜不同雙金屬氧化物催化型顆粒捕集器(CDPF)樣品水熱老化狀態(tài)下的理化特性與催化活性。結(jié)果表明:摻雜Ce-Zr雙金屬氧化物的CDPF樣品物相結(jié)構(gòu)和晶胞參數(shù)穩(wěn)定性較好,摻雜Zr-Fe雙金屬氧化物的CDPF樣品能較好地抑制老化后載體表面貴金屬分散度的降低程度。摻雜Fe-Ce和Zr-Fe的CDPF樣品在高溫老化過程中分散的金屬氧化物會(huì)再次發(fā)生固溶而形成較多的固溶體,帶來更多氧空位。經(jīng)歷高溫水熱老化后,CDPF樣品的還原峰均不同程度地向高溫方向遷移,其中摻雜Fe-Ce的CDPF樣品還原峰遷移幅度較低,摻雜Ce-Zr的CDPF樣品還原峰向遷移幅度較大。摻雜Fe-Ce和Zr-Fe的CDPF樣品老化后對(duì)CO的氧化活性較高,劣化程度較小,并且保持較好的NO催化選擇性。摻雜Ce-Zr的CDPF樣品老化后對(duì)C3H8氧化活性略有下降。

    Abstract:

    Based on XRD, XPS, H2-TPR and other characterization methods for physical and chemical properties and catalyst activity evaluation methods, the physical and chemical properties and catalytic activity of CDPF samples doped with different bimetal oxide under hydrothermal aging condition were studied. The results show that Ce-Zr bimetal oxide doped sample has good stability in phase structure and cell parameters, Zr-Fe bimetal oxide doped sample can better inhibit the dispersity of noble metal on carrier’s surface. For Fe-Ce and Zr-Fe bimetal oxide doped CDPF samples, during high-temperature aging process, the dispersed metal oxides undergo solid solution again, which will cause a formation of solid solution and more oxygen vacancies. After experiencing high-temperature hydrothermal aging process, the diffraction characteristic peaks of samples all migrate various degrees towards the high-temperature direction. Fe-Ce bimetal oxide doped sample shows a low degree of migration while Ce-Zr bimetal oxide doped sample is higher. Fe-Ce and Zr-Fe bimetal oxide doped aged samples showed higher oxidation activity of CO and show a low-level degradation. Ce-Zr bimetal oxide doped aged sample showed a slight decrease in the oxidation activity of C3H8. The catalytic activity for NO of Ce-Zr bimetal oxide doped sample decreases slightly after high-temperature hydrothermal aging process.

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引用本文

張?jiān)嗜A,鄭森,樓狄明,房亮,馮謙.雙金屬氧化物摻雜對(duì)CDPF老化性能的影響[J].稀有金屬材料與工程,2024,53(5):1391~1400.[Zhang Yunhua, Zheng Sen, Lou Diming, Fang Liang, Feng Qian. Effect of bimetal oxide doping on the aging performance of catalyzed DPF[J]. Rare Metal Materials and Engineering,2024,53(5):1391~1400.]
DOI:10.12442/j. issn.1002-185X.20230334

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  • 收稿日期:2023-05-31
  • 最后修改日期:2023-08-24
  • 錄用日期:2023-08-24
  • 在線發(fā)布日期: 2024-05-28
  • 出版日期: 2024-05-22