2,溫度對TiO2的類型沒有明顯影響。純鈦焊接接頭的氧化過程可描述為:氧氣在表面被吸收;氧化物優(yōu)先在缺陷區(qū)形核;氧化物橫向生長、增厚。在較高溫度下,氧化膜中出現(xiàn)裂紋或空隙,成為O原子傳輸通道,導致O和Ti原子的高擴散速率和氧化速率。"/>

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純鈦TIG焊接接頭的高溫氧化行為
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1.中國石油集團工程材料研究院有限公司 油氣鉆采輸送裝備全國重點實驗室,陜西 西安 710077;2.西安石油大學 材料科學與工程學院,陜西 西安 710065;3.西安交通大學 材料科學與工程學院 金屬材料強度國家重點實驗室,陜西 西安 710049

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High Temperature Oxidation Behavior of Pure Ti TIG Welded Joint
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1.National Key Laboratory of Oil and Gas Drilling and Transportation Equipment, Tubular Goods Research Institute of China National Petroleum Corporation, Xi'an 710077, China;2.School of Materials Science and Engineering, Xi'an Shiyou University, Xi'an 710065, China;3.State Key Laboratory for Mechanical Behavior of Materials, School of Materials Science and Engineering, Xi'an Jiaotong University, Xi'an 710049, China

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Program of Key Technologies on Evaluation and Repair of Casing Damaging in Oil and Gas Well (2021DJ2705)

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    摘要:

    對純鈦氬弧焊焊接接頭在550 ℃下氧化不同時間(2,4,6,8 h)以及在不同溫度(650,750,850,950 ℃)下氧化4 h的氧化動力學、氧化形態(tài)和氧化產(chǎn)物進行了研究。結(jié)果表明,在550 ℃下,氧化時間對焊接接頭氧化行為的影響有限,而氧化溫度對純鈦焊接接頭的氧化行為有顯著影響,且溫度越高,氧化越嚴重。在低溫下,純鈦焊接接頭的氧化動力學接近準線性定律,隨著溫度升高,氧化速率呈指數(shù)增長。此外,焊接接頭表面產(chǎn)生的氧化產(chǎn)物是具有銳鈦礦和金紅石結(jié)構(gòu)的TiO2,溫度對TiO2的類型沒有明顯影響。純鈦焊接接頭的氧化過程可描述為:氧氣在表面被吸收;氧化物優(yōu)先在缺陷區(qū)形核;氧化物橫向生長、增厚。在較高溫度下,氧化膜中出現(xiàn)裂紋或空隙,成為O原子傳輸通道,導致O和Ti原子的高擴散速率和氧化速率。

    Abstract:

    The oxidation behavior, oxidation morphology, and oxidation products of pure Ti joint welded by tungsten inert gas welding technique at 550 °C for different durations (2, 4, 6, and 8 h) and those at different temperatures (650, 750, 850, and 950 °C) for 4 h were investigated. Results show that at 550 °C, the oxidation time has a slight influence on the oxidation behavior of welded joint. The oxidation temperature has a significant impact on the oxidation behavior, and the higher the temperature, the more severe the oxidation of welded joints. The oxidation kinetics is very close to the quasi-linear law at low temperatures. With increasing the temperature, the oxidation rate is increased exponentially. Additionally, the oxidation products generated on the surface of welded joint are TiO2 with anatase and rutile structures, and the temperature barely has effect on the TiO2 type. The oxidation process of pure Ti welded joint can be described as follows: oxygen atoms are absorbed on the surface; oxides preferentially nucleate in the defective zone; oxides grow laterally and the oxidation film becomes thicker. At relatively higher temperatures, the cracks or voids appear in the oxidation film, which become the transmission channels of O atoms, leading to the high diffusion rate of O and Ti atoms and high oxidation rate.

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韓禮紅,楊尚諭,王建軍,雒設計,李丹,劉明.純鈦TIG焊接接頭的高溫氧化行為[J].稀有金屬材料與工程,2024,53(2):350~356.[Han Lihong, Yang Shangyu, Wang Jianjun, Luo Sheji, Li Dan, Liu Ming. High Temperature Oxidation Behavior of Pure Ti TIG Welded Joint[J]. Rare Metal Materials and Engineering,2024,53(2):350~356.]
DOI:10.12442/j. issn.1002-185X.20230291

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  • 收稿日期:2023-05-15
  • 最后修改日期:2023-06-25
  • 錄用日期:2023-06-28
  • 在線發(fā)布日期: 2024-02-27
  • 出版日期: 2024-02-23