-1條件下的熱壓縮變形行為,分析了熱壓縮過程中該合金的微觀組織特征,并基于峰值應力構建了其熱變形本構模型。結果表明,應變速率和變形溫度對Zr-1.0Ti-0.35Nb合金熱變形過程具有顯著影響,流變應力隨應變速率增加而增大,隨變形溫度的增加而減小,達到峰值應力后流變曲線呈現(xiàn)明顯動態(tài)再結晶特征;提高變形溫度有助于發(fā)生動態(tài)再結晶和晶粒長大;基于Arrhenius本構方程計算得到Zr-1.0Ti-0.35Nb合金的熱變形激活能為225.8 kJ/mol,硬化指數(shù)為5.62,說明合金元素Ti使鋯合金的熱變形激活能升高;實驗值與預測值之間的相關系數(shù)為0.97,平均相對誤差為6.15%,證實此本構方程預測Zr-1.0Ti-0.35Nb合金流變應力的準確性,能夠為新型鋯合金熱加工工藝優(yōu)化提供理論指導。"/>

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Zr-1.0Ti-0.35Nb合金熱變形行為研究
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作者單位:

1.西北工業(yè)大學材料學院;2.中機第一設計研究院有限公司

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基金項目:

國家自然科學基金(12005170,U2067217, U2230124),國防科技工業(yè)局乏燃料后處理科研專項


Investigations on Hot Deformation Behavior of Zr-1.0Ti-0.35Nb
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Affiliation:

1.School of Materials Science and Engineering,Northwestern Polytechnical University,Xi’an;2.First Design and Research institure MI China Co,Ltd

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    摘要:

    乏燃料后處理強酸、強氧化性、強放射性的工作環(huán)境,對后處理溶解器選材、加工工藝提出了嚴苛要求。本論文研究了自主設計Zr-1.0Ti-0.35Nb合金在670 ~ 750 ℃溫度范圍、三種不同應變速率0.01、0.1和1 s-1條件下的熱壓縮變形行為,分析了熱壓縮過程中該合金的微觀組織特征,并基于峰值應力構建了其熱變形本構模型。結果表明,應變速率和變形溫度對Zr-1.0Ti-0.35Nb合金熱變形過程具有顯著影響,流變應力隨應變速率增加而增大,隨變形溫度的增加而減小,達到峰值應力后流變曲線呈現(xiàn)明顯動態(tài)再結晶特征;提高變形溫度有助于發(fā)生動態(tài)再結晶和晶粒長大;基于Arrhenius本構方程計算得到Zr-1.0Ti-0.35Nb合金的熱變形激活能為225.8 kJ/mol,硬化指數(shù)為5.62,說明合金元素Ti使鋯合金的熱變形激活能升高;實驗值與預測值之間的相關系數(shù)為0.97,平均相對誤差為6.15%,證實此本構方程預測Zr-1.0Ti-0.35Nb合金流變應力的準確性,能夠為新型鋯合金熱加工工藝優(yōu)化提供理論指導。

    Abstract:

    The harsh environment with strong acid, high oxidability and irradiation raises urgent demand for advanced structural materials used for reprocessing dissolver of spent nuclear fuels. In this paper, hot compression behavior of a Zr-1.0Ti-0.35Nb alloy was investigated at the strain rates of 0.01, 0.1, 1 s-1 and in the temperature range of 670 ~750 °C. Microstructural evolution during the hot compression was analyzed. The results reveal that the strain rate and deformation temperature both significantly affect the hot deformation behaviour of Zr-1.0Ti-0.35Nb alloy. Flow stress increases with accelerated strain rate, and decreases with elevated temperature. Beyond peak stress, the flow curve exhibits apparent characteristic of dynamic recrystallization characteristics. Elevated deformation temperature favors dynamic recrystallization and grain growth. An Arrhenius-type constitutive model was established based on the obtained peak stress values, in which the activation energy is calculated as 225.8 kJ/mol suggesting a Ti-induced elevation of activation energy and the hardening index is 5.62. A correlation coefficient of 0.97427 and average relative error of 6.15% are obtained between the experimental and predicted values, demonstrating sound applicability of the constitutive model that is expected to guide processing optimization for the new Zr-1.0Ti-0.35Nb alloy.

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公維佳,陳吉昌,張敬翊,陳兆奎,李中奎,李金山. Zr-1.0Ti-0.35Nb合金熱變形行為研究[J].稀有金屬材料與工程,2024,53(6):1608~1615.[GONG Weijia, CHEN Jichang, ZHANG Jingyi, CHEN Zhaokui, LI Zhongkui, LI Jinshan. Investigations on Hot Deformation Behavior of Zr-1.0Ti-0.35Nb[J]. Rare Metal Materials and Engineering,2024,53(6):1608~1615.]
DOI:10.12442/j. issn.1002-185X.20230207

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  • 收稿日期:2023-04-13
  • 最后修改日期:2023-06-02
  • 錄用日期:2023-06-26
  • 在線發(fā)布日期: 2024-06-24
  • 出版日期: 2024-06-17