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基于小沖桿試驗(yàn)技術(shù)評(píng)估充氫鋯合金材料的拉伸性能
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1.清華大學(xué)核能與新能源技術(shù)研究院;2.清華大學(xué)材料學(xué)院先進(jìn)材料教育部重點(diǎn)實(shí)驗(yàn)室;3.北京師范大學(xué)核科學(xué)與技術(shù)學(xué)院射線束技術(shù)教育部重點(diǎn)實(shí)驗(yàn)室

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Evaluation of Tensile Properties of Hydrogen-charged Zirconium Alloy Materials Based on Small Punch Test Technique
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    摘要:

    鋯合金由于具有良好的機(jī)械性能、耐腐蝕性能等而被用作反應(yīng)堆內(nèi)燃料元件的包殼材料。然而,Zr-4已不能滿足核電技術(shù)在更高燃耗條件下的使用要求,因此,通過(guò)調(diào)控合金成分開發(fā)新型鋯合金具有重要意義。本研究對(duì)Zr-4以及其他兩種新型鋯合金材料在室溫、315℃條件下進(jìn)行常規(guī)拉伸試驗(yàn),結(jié)合計(jì)算結(jié)果分析了成分差異造成的沉淀相改變,提出了析出強(qiáng)化機(jī)制對(duì)于鋯合金性能提升的重要意義。首次利用小沖桿試驗(yàn)對(duì)鋯合金原樣的力學(xué)性能進(jìn)行測(cè)試,該工作確定了常規(guī)拉伸試驗(yàn)與小沖桿試驗(yàn)結(jié)果之間的經(jīng)驗(yàn)公式中與鋯合金材料本身相關(guān)的系數(shù)數(shù)值,驗(yàn)證了小沖桿試驗(yàn)用于鋯合金拉伸性能評(píng)估的可行性。利用氣相滲氫法在400℃對(duì)Zr-4以及其他兩種新型鋯合金進(jìn)行充氫處理,并利用小沖桿試驗(yàn)對(duì)鋯合金充氫試樣的力學(xué)性能進(jìn)行測(cè)試。結(jié)果顯示,充氫鋯合金在載荷-位移曲線的塑性失穩(wěn)階段出現(xiàn)“平臺(tái)區(qū)”特殊現(xiàn)象。本論文對(duì)該現(xiàn)象進(jìn)行探究,用金相分析表征了氫化物的形貌特征并對(duì)其含量進(jìn)行了定量估算,推測(cè)氫化物與基體斷裂韌性上的差異、氫化物相特殊的長(zhǎng)鏈構(gòu)型以及強(qiáng)取向性與這一現(xiàn)象有著重要關(guān)聯(lián)。

    Abstract:

    Zirconium alloys are used as cladding materials for fuel components in reactors due to their excellent mechanical properties, excellent corrosion resistance and low thermal neutron absorption cross-section. However, Zr-4 can no longer reach the requirements of nuclear power technology under higher burn-up conditions. Therefore, it is of great significance to develop new zirconium alloys by regulating the alloy composition. In this study, Zr-4 and two other new zirconium alloy materials were subjected to conventional tensile tests at room temperature and 315℃. The precipitation phase changes caused by composition differences were analyzed based on the calculation results. And the importance of precipitation strengthening mechanism was proposed for the performance improvement of zirconium alloys. The mechanical properties of zirconium alloy were tested for the first time by using small punch test. The coefficient values related to the zirconium alloy material itself were determined in the empirical formula between the conventional tensile test and the small punch test. The feasibility of the small punch test for the evaluation of the tensile properties of zirconium alloys was verified. Zr-4 and two other new zirconium alloys were hydrogen-charged at 400°C by gaseous hydrogen permeation, and their mechanical properties were tested by SPT. The results show that the hydrogen-charged Zr alloys have a special phenomenon of "platform region" in the plastic instability stage of the load-displacement curve. In this paper, the morphological characteristics of hydrides were characterized by metallographic analysis and their contents was quantitatively estimated. It was speculated that the difference in the fracture toughness between hydrides and matrix, the special long chain configuration of the hydride phase and its strong orientation have an important correlation with this phenomenon.

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魏雅璇,王鼎渠,李正操,呂沙沙.基于小沖桿試驗(yàn)技術(shù)評(píng)估充氫鋯合金材料的拉伸性能[J].稀有金屬材料與工程,2024,53(6):1601~1607.[Wei Yaxuan, Wang Dingqu, Li Zhengcao, Lv Shasha. Evaluation of Tensile Properties of Hydrogen-charged Zirconium Alloy Materials Based on Small Punch Test Technique[J]. Rare Metal Materials and Engineering,2024,53(6):1601~1607.]
DOI:10.12442/j. issn.1002-185X.20230178

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  • 收稿日期:2023-04-03
  • 最后修改日期:2023-06-14
  • 錄用日期:2023-06-25
  • 在線發(fā)布日期: 2024-06-24
  • 出版日期: 2024-06-17