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氫對(duì)鋯合金模擬LOCA試驗(yàn)后殘余塑性的影響
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中國(guó)原子能科學(xué)研究院

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中核集團(tuán)領(lǐng)創(chuàng)科研項(xiàng)目(LC202309000320)


Effect of Hydrogen on Residual Plasticity of Zr-Sn-Nb Alloy after LOCA
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China Institute of Atomic Energy

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    摘要:

    鋯合金包殼在堆內(nèi)吸氫,失水事故(LOCA)鋯合金包殼會(huì)脆化,含氫包殼在事故進(jìn)程或事故后續(xù)處理中更易破裂,造成放射性產(chǎn)物泄漏。文章對(duì)不同氫含量(0ppm、195ppm、310ppm、395ppm)鋯合金模擬LOCA試驗(yàn)后殘余塑性進(jìn)行研究,探索了氫對(duì)鋯合金模擬LOCA試驗(yàn)后殘余塑性的影響機(jī)理。結(jié)果表明,隨含氫量的提高,在模擬LOCA試驗(yàn)后鋯合金殘余塑性下降。氫的加入對(duì)鋯合金顯微組織結(jié)構(gòu)影響較小,氫對(duì)鋯合金微觀組織結(jié)構(gòu)的影響不是導(dǎo)致鋯合金殘余塑性降低原因。氫的存在導(dǎo)致鋯合金模擬LOCA試驗(yàn)后殘余塑性下降的原因之一是氫增加造成鋯合金prior-β相中吸收氧含量提高,從而降低鋯合金殘余塑性,其次氫可能以飽和固溶或細(xì)小的氫化物脆性相方式存在于prior-β相中,也造成鋯合金殘余塑性下降。

    Abstract:

    Zirconium cladding absorbs hydrogen in the reactor, and the zirconium cladding will embrittlement in the Loss Of Coolant Accident(LOCA). The hydrogen-containing cladding is more likely to rupture in the process of accident or the subsequent treatment of accident, resulting in the leakage of radioactive products. In this thesis, residual plasticity of zirconium alloys with different hydrogen contents (0 ppm, 195 ppm, 315 ppm, 395 ppm) after simulated LOCA was studied, and the effect mechanism of hydrogen on residual plasticity of zirconium alloys during simulated LOCA was explored. The results show that the residual plasticity of zirconium alloy decreases with the increase of hydrogen content. The increase of hydrogen has little effect on the microstructure of zirconium alloy, and the effect of hydrogen on the microstructure of zirconium alloy is not the reason for the reduction of residual plasticity of zirconium alloy. one of the reasons why the presence of hydrogen leads to the decrease of the residual plasticity of zirconium alloy after simulated LOCA is that the increase of hydrogen leads to the increase of oxygen content absorbed by the prior-β phase after quenching, thus reducing the residual plasticity of zirconium alloy. Secondly, hydrogen may exist in the prior-β phase in the form of saturated solid solution or fine hydride brittle phase, which also leads to the decrease of the residual plasticity of zirconium alloy.

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劉鑫,涂蒙河,李燊,王輝,胡勇.氫對(duì)鋯合金模擬LOCA試驗(yàn)后殘余塑性的影響[J].稀有金屬材料與工程,2024,53(6):1626~1631.[Liu Xin, Tu Menghe, Li Shen, Wang Hui, Hu Yong. Effect of Hydrogen on Residual Plasticity of Zr-Sn-Nb Alloy after LOCA[J]. Rare Metal Materials and Engineering,2024,53(6):1626~1631.]
DOI:10.12442/j. issn.1002-185X.20230177

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  • 收稿日期:2023-04-03
  • 最后修改日期:2023-06-25
  • 錄用日期:2023-06-28
  • 在線發(fā)布日期: 2024-06-24
  • 出版日期: 2024-06-17