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電積鈷板微觀組織結(jié)構(gòu)及力學(xué)性能對(duì)比
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作者單位:

1.蘭州理工大學(xué) 省部共建有色金屬先進(jìn)加工與再利用國(guó)家重點(diǎn)實(shí)驗(yàn)室,甘肅 蘭州 730050;2.蘭州理工大學(xué) 材料科學(xué)與工程學(xué)院,甘肅 蘭州 730050;3.蘭州理工大學(xué) 白銀新材料研究院,甘肅 白銀 730900

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通訊作者:

中圖分類號(hào):

TG146.1+6

基金項(xiàng)目:

National Natural Science Foundation of China (No. 52261011); Industrial Support Program for Higher Education Institutions in Gansu Province (No. 2022CYZC-19); Gansu Province Key R&D Program Projects (No. 21YF5GD186)


Comparison of Microstructure and Mechanical Properties of Electrodeposited Cobalt Plates
Author:
Affiliation:

1.State Key Laboratory of Advanced Processing and Recycling of Nonferrous Metals, Lanzhou University of Technology, Lanzhou 730050, China;2.School of Materials Science and Engineering, Lanzhou University of Technology, Lanzhou 730050, China;3.Baiyin New Materials Research Institute, Lanzhou University of Technology, Baiyin 730900, China

Fund Project:

National Natural Science Foundation of China (52261011); Industrial Support Program for Higher Education Institutions in Gansu Province (2022CYZC-19); Gansu Province Key R&D Program Projects (21YF5GD186)

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    摘要:

    研究了3種電積鈷板的微觀組織結(jié)構(gòu)和力學(xué)性能之間的差異,采用X射線衍射儀和掃描電子顯微鏡分析了3種電積鈷板的擇優(yōu)取向、晶體結(jié)構(gòu)和微觀組織形貌;并分析了3種電積鈷板的強(qiáng)度、硬度和韌性。結(jié)果表明:3種電積鈷板均是密排六方結(jié)構(gòu)(hcp)的純鈷相,晶粒取向隨機(jī)。A-Co板沉積層均勻致密、孔洞較少,而B-Co板和C-Co板的沉積層較為分散且存在大量的孔洞。同時(shí)A-Co板表面的平均晶粒尺寸最小,沉積層晶粒大小分布均勻,B-Co板表面的平均晶粒尺寸最大,沉積層晶粒大小分布不均勻。3種電積鈷板截面的始極片都是柱狀晶結(jié)構(gòu),且始極片兩側(cè)的生長(zhǎng)方式不同。由力學(xué)性能分析發(fā)現(xiàn)A-Co板的抗拉強(qiáng)度和硬度均高于其它2種鈷板,但是韌性較差。綜上所述,A-Co板的品質(zhì)要明顯優(yōu)于B-Co板和C-Co板的品質(zhì)。

    Abstract:

    In order to study the differences in microstructure and mechanical properties of three kinds of electrodeposited cobalt plates, the preferred orientation, crystal structure, and microstructure of each plate were analyzed by X-ray diffractometer and scanning electron microscope. Furthermore, the mechanical properties of electrodeposited cobalt plates were tested, including their strength, hardness, and toughness. The results show that all of the plates are pure cobalt phases with a close-packed hexagonal structure (hcp) and random grain orientation. The deposition layer of the A-Co plate is uniform and dense with few holes, while those of the B-Co and C-Co plates grow apart and has a large number of holes. Meanwhile, the average grain size on the surface of the A-Co plate is the smallest, and the grain size distribution of the deposited layer is uniform, while that of the B-Co plate is the largest, and the grain size distribution of the deposited layer is not uniform. The starting sheets of the three electrodeposited cobalt plate cross-sections are all columnar crystal structures, and the growth patterns of the two sides of the starting sheets are different. From the analysis of mechanical properties, it is found that the tensile strength and hardness of the A-Co plate are higher than those of other two cobalt plates, but the toughness is lower. In conclusion, the quality of A-Co plates is significantly better than that of B-Co plates and C-Co plates.

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徐仰濤,代靖民,裴亮,彭尹,杜海洋.電積鈷板微觀組織結(jié)構(gòu)及力學(xué)性能對(duì)比[J].稀有金屬材料與工程,2023,52(10):3387~3398.[Xu Yangtao, Dai Jingmin, Pei Liang, Peng Yin, Du Haiyang. Comparison of Microstructure and Mechanical Properties of Electrodeposited Cobalt Plates[J]. Rare Metal Materials and Engineering,2023,52(10):3387~3398.]
DOI:10.12442/j. issn.1002-185X.20230121

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歷史
  • 收稿日期:2023-03-09
  • 最后修改日期:2023-04-19
  • 錄用日期:2023-04-27
  • 在線發(fā)布日期: 2023-10-26
  • 出版日期: 2023-10-24