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U-Nb合金低溫分解機(jī)制的相場法研究
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中國工程物理研究院 材料研究所,四川 江油 621907

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國家自然科學(xué)青年基金(51901210);中物院創(chuàng)新發(fā)展基金(CX20210008)


Phase-Field Study of Low-Temperature Decomposition Mechanism in U-Nb Alloys
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Affiliation:

Institute of Materials, China Academy of Engineering Physics, Jiangyou 621907, China

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National Natural Science Foundation of China (51901210); Project Supported by CAEP Foundation (CX20210008)

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    摘要:

    低溫時效處理導(dǎo)致U-Nb合金的力學(xué)性能發(fā)生顯著改變,利用相場法研究了性能變化對應(yīng)的微觀組織演化。結(jié)果表明,在較高溫度可能發(fā)生調(diào)幅分解,但必須滿足其熱力學(xué)條件,而且也僅出現(xiàn)在初期。發(fā)生普通型析出的范圍可能更廣,因為合金成分接近于發(fā)生結(jié)構(gòu)轉(zhuǎn)變的臨界成分,時效對應(yīng)的母相無論是類高溫立方相還是類低溫正交相,穩(wěn)定核胚和母相之間的Nb含量差異都可以相當(dāng)小。當(dāng)相界面的遷移率較大而擴(kuò)散率較低時,處于長大階段的析出物的Nb含量明顯不同于平衡態(tài)成分。因此,U-Nb合金的低溫時效硬化效應(yīng)可能是由相分解引起的Nb再分配所導(dǎo)致。

    Abstract:

    The microstructure evolution responsible for significant change of mechanical properties during low-temperature aging of U-Nb alloys was investigated by phase-field method. Results show that spinodal decomposition may occur at the early stage only when its thermodynamic condition is satisfied. Possibilities of general precipitation widely exist at low-temperature region, where the Nb content difference between the stable nucleus and the matrix can be significantly small, no matter the matrix of aging is cubic-like phase or in the orthorhombic-like phase, because the alloy composition is close to the critical composition of structural transition. At low diffusion rate and the relatively high mobility of phase interface, the Nb content of growing precipitates is far away from equilibrium composition. It is suggested that the Nb redistribution caused by phase decomposition may be responsible for the low-temperature aging hardening effect in U-Nb alloys.

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崔書山,施韜,路超,尹嘉清,蘇斌.U-Nb合金低溫分解機(jī)制的相場法研究[J].稀有金屬材料與工程,2023,52(10):3374~3381.[Cui Shushan, Shi Tao, Lu Chao, Yin Jiaqing, Su Bin. Phase-Field Study of Low-Temperature Decomposition Mechanism in U-Nb Alloys[J]. Rare Metal Materials and Engineering,2023,52(10):3374~3381.]
DOI:10.12442/j. issn.1002-185X.20230112

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  • 收稿日期:2023-03-05
  • 最后修改日期:2023-06-12
  • 錄用日期:2023-06-26
  • 在線發(fā)布日期: 2023-10-26
  • 出版日期: 2023-10-24