0.7+Cr23C6+ZrO2。涂層的晶粒得到了明顯細(xì)化,實(shí)現(xiàn)了晶界強(qiáng)化、固溶強(qiáng)化和彌散強(qiáng)化(Orowan)的共同作用,形成的碳化物Cr23C6相與FCC固溶體結(jié)合形成共晶碳化物,起到了協(xié)同強(qiáng)化作用,有效地提高了涂層的硬度和耐磨性。然而ZrC中的Zr與空氣中的雜質(zhì)O結(jié)合生成的ZrO2也對(duì)涂層的性能產(chǎn)生了不利影響,主要是因?yàn)閆rO2的存在會(huì)導(dǎo)致涂層中顆粒分布不均勻加劇,弱化彌散強(qiáng)化的作用。所以當(dāng)ZrC較少時(shí),涂層的性能并未得到較好的提升,但是當(dāng)涂層中ZrC含量增加到5wt.%時(shí),涂層中析出了較多的強(qiáng)化相ZrC0.7能夠有效的提高材料的性能,該涂層的最大硬度為651±15 HV0.1,摩擦系數(shù)為0.161,相較于不含ZrC的涂層均有較大的提升。"/>

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ZrC增強(qiáng)激光熔覆CoCrNi合金熔覆層的組織及性能
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1.北方工業(yè)大學(xué)機(jī)械與材料工程學(xué)院;2.浙江機(jī)電職業(yè)技術(shù)學(xué)院

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國家自然科學(xué)基金項(xiàng)目(項(xiàng)目編號(hào):51074204)


Microstructure and Properties of ZrC Enhanced Laser Cladding CoCrNi Alloy Cladding Layer
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1.School of Mechanical and Materials Engineering,North China University of Technology;2.Zhejiang Institute of Mechanical Electrical Engineering

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    摘要:

    本研究采用激光熔覆技術(shù),在低碳鋼表面制備了ZrC增強(qiáng)的CoCrNi合金涂層。研究了ZrC的不同分?jǐn)?shù)(0, 1, 3, 5 wt.%)對(duì)CoCrNi基中熵合金涂層組織、硬度和耐磨性的影響。利用X射線衍射儀、掃描電鏡和能譜儀分析了涂層的相組成及微觀組織結(jié)構(gòu),并采用顯微硬度和摩擦磨損試驗(yàn)對(duì)樣品的硬度和耐磨性進(jìn)行了測(cè)試。結(jié)果表明:熔覆層與基體形成了良好的冶金結(jié)合,沒有出現(xiàn)明顯的裂紋和及空洞等缺陷。不含ZrC的CoCrNi中熵合金涂層由單相FCC結(jié)構(gòu)組成,隨著涂層中ZrC的加入,涂層中的物相組成變?yōu)榱薋CC+ ZrC0.7+Cr23C6+ZrO2。涂層的晶粒得到了明顯細(xì)化,實(shí)現(xiàn)了晶界強(qiáng)化、固溶強(qiáng)化和彌散強(qiáng)化(Orowan)的共同作用,形成的碳化物Cr23C6相與FCC固溶體結(jié)合形成共晶碳化物,起到了協(xié)同強(qiáng)化作用,有效地提高了涂層的硬度和耐磨性。然而ZrC中的Zr與空氣中的雜質(zhì)O結(jié)合生成的ZrO2也對(duì)涂層的性能產(chǎn)生了不利影響,主要是因?yàn)閆rO2的存在會(huì)導(dǎo)致涂層中顆粒分布不均勻加劇,弱化彌散強(qiáng)化的作用。所以當(dāng)ZrC較少時(shí),涂層的性能并未得到較好的提升,但是當(dāng)涂層中ZrC含量增加到5wt.%時(shí),涂層中析出了較多的強(qiáng)化相ZrC0.7能夠有效的提高材料的性能,該涂層的最大硬度為651±15 HV0.1,摩擦系數(shù)為0.161,相較于不含ZrC的涂層均有較大的提升。

    Abstract:

    ZrC strengthened CoCrNi-based laser cladded coatings with different content of ZrC were prepared on the surface of low carbon steel. The effects of ZrC addition on microstructure, hardness and wear resistance of CoCrni-based medium entropy alloy coating were investigated. The results show that there is a good metallurgical bond between the cladding layer and the matrix without obvious cracks and defects. The CoCrNi alloy coating without ZrC is composed of single-phase FCC structure. With the addition of ZrC in the coating, the coating phase compositions change to FCC+ ZrC0.7+Cr23C6+ZrO2 multiple phase structures. The grains of the coating were significantly refined, and the combination of grain boundary strengthening, solution strengthening and dispersion strengthening (Orowan) was realized, which effectively improved the hardness and wear resistance of the coating. However, ZrO2 produced by the combination of Zr in ZrC and O in the air also has an adverse effect on the performance of the coating, mainly because the presence of ZrO2 will cause the uneven distribution of particles in the coating and weaken the effect of dispersion strengthening. Therefore, when the content of ZrC is small, the performance of the coating is not improved. However, when ZrC content in the coating increases to 5wt.%, more ZrC0.7 phase is separated out from the coating, which can effectively improve the performance of the material. The hardness is 651±15 HV0.1 and the friction coefficient is 0.161 which is much lower owing to the synergetic strengthening effect.

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劉冉,黨鮮婷,陳楚琦,吳韜. ZrC增強(qiáng)激光熔覆CoCrNi合金熔覆層的組織及性能[J].稀有金屬材料與工程,2024,53(3):778~786.[Ran Liu, Xianting Dang, Chuqi Chen, Tao Wu. Microstructure and Properties of ZrC Enhanced Laser Cladding CoCrNi Alloy Cladding Layer[J]. Rare Metal Materials and Engineering,2024,53(3):778~786.]
DOI:10.12442/j. issn.1002-185X.20230107

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  • 收稿日期:2023-03-03
  • 最后修改日期:2023-04-26
  • 錄用日期:2023-04-27
  • 在線發(fā)布日期: 2024-03-27
  • 出版日期: 2024-03-20