1.33和H0.62Zr0.38。由此可見,過渡區(qū)中的氫化物對改善鋯的吸氫性能起著重要作用。通過對動力學機制進行研究,確定在室溫下,鍍鈀且退火處理后的鋯合金吸氫過程符合一維擴散機制;而在250 ℃時,符合二維擴散機制。"/>

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電鍍鈀對鋯合金吸氫性能的影響
作者:
作者單位:

1.北京科技大學 新金屬材料國家重點實驗室,北京 100083;2.中石油工程技術(shù)研發(fā)有限公司,北京 102206;3.北京浩運金能新能源材料科技有限公司,北京 102100

作者簡介:

Song Xiping, Ph. D., Professor, State Key Laboratory for Advanced Metals and Materials, University of Science and Technology Beijing, Beijing 100083, P. R. China, Tel: 0086-10-62333213, E-mail: xpsong@skl.ustb.edu.cn

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基金項目:

國家自然科學基金項目(No. 21171018 and 51271021);新金屬材料國家重點實驗室 (2019-ZD06 and 2021Z-18).


Effect of Palladium Electroplating on Hydrogen Absorption Properties of Zirconium Alloy
Author:
Affiliation:

1.State Key Laboratory for Advanced Metals and Materials, University of Science and Technology Beijing, Beijing 100083, China;2.CNPC Engineering Technology R&D Company Limited, Beijing 102206, China;3.Whole Win (Beijing) Materials Sci. and Tech. Co., Ltd, Beijing 102100, China

Fund Project:

National Natural Science Foundation of China (21171018, 51271021); Supported by State Key Laboratory for Advanced Metals and Materials (2019-ZD06, 2021Z-18)

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    摘要:

    鋯具有良好的吸氫性能,被認為是儲氘領(lǐng)域的候選材料。但由于其吸氫溫度較高且吸氫動力學較慢,目前尚不能進行廣泛應用。采用電鍍鈀的方法對鋯進行表面改性,以提高其吸氫性能。結(jié)果表明:在經(jīng)過鍍鈀且退火處理后的鋯合金,在室溫下可以實現(xiàn)吸氫,并且有適當?shù)脑杏冢慌c此同時,隨著溫度的升高,鍍鈀且退火處理后的鋯合金孕育期縮短,吸氫速率變快。通過對微觀結(jié)構(gòu)進行分析,發(fā)現(xiàn)在氫化后,鈀層與鋯基板之間形成了過渡區(qū),過渡區(qū)中存在PdH1.33和H0.62Zr0.38。由此可見,過渡區(qū)中的氫化物對改善鋯的吸氫性能起著重要作用。通過對動力學機制進行研究,確定在室溫下,鍍鈀且退火處理后的鋯合金吸氫過程符合一維擴散機制;而在250 ℃時,符合二維擴散機制。

    Abstract:

    Zirconium is an excellent hydrogen absorption material and has been regarded as a candidate material in the deuterium storage field. However, due to its higher hydrogen absorption temperature and slower hydrogen absorption kinetics, it cannot be applied at present. Palladium electroplating was used as a surface modification to improve the property. The results show that after the palladium electroplating and annealing, the zirconium alloy can absorb hydrogen at room temperature with an appropriate incubation period. With the increase in temperature, the hydrogen absorption rate becomes faster with a shorter incubation period. A transition zone forms between the palladium layer and zirconium substrate, and PdH1.33 and H0.62Zr0.38 are found in the transition zone after hydrogenation. These hydride phases in the transition zone play an important role in improving the hydrogen absorption property of zirconium. For the kinetics mechanism, it is determined to be 1-D diffusion at room temperature and 2-D diffusion at 250 °C.

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趙立功,李江豪,郭慧娟,楊大穩(wěn),張岸佳,張沛龍,周文嬌,佟歡,宋西平.電鍍鈀對鋯合金吸氫性能的影響[J].稀有金屬材料與工程,2024,53(3):685~691.[Zhao Ligong, Li Jianghao, Guo Huijuan, Yang Dawen, Zhang Anjia, Zhang Peilong, Zhou Wenjiao, Tong Huan, Song Xiping. Effect of Palladium Electroplating on Hydrogen Absorption Properties of Zirconium Alloy[J]. Rare Metal Materials and Engineering,2024,53(3):685~691.]
DOI:10.12442/j. issn.1002-185X.20230102

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  • 收稿日期:2023-03-01
  • 最后修改日期:2023-07-24
  • 錄用日期:2023-07-24
  • 在線發(fā)布日期: 2024-03-22
  • 出版日期: 2024-03-20