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質(zhì)子交換膜燃料電池極板及其表面改性研究進(jìn)展
作者:
作者單位:

西安工業(yè)大學(xué) 材料與化工學(xué)院 西安 710021

作者簡(jiǎn)介:

通訊作者:

中圖分類號(hào):

TG174.4; MT911.4

基金項(xiàng)目:

國(guó)家自然科學(xué)基金資助(No.52101094),中國(guó)博士后科學(xué)基金資助項(xiàng)目 No.2020M683670XB,陜西省教育廳科研計(jì)劃項(xiàng)目資助(項(xiàng)目編號(hào):21JP053)


Research progress on surface modification of bipolar plates for proton exchange membrane fuel cells
Author:
Affiliation:

Xi'an Technological University

Fund Project:

National Natural Science Foundation of China Program (No.52101094)

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    摘要:

    在質(zhì)子交換膜燃料電池(Proton exchange membrane fuel cells,PEMFCs)的部件中,雙極板是重要組成部分。雙極板約占燃料電池成本、質(zhì)量、體積的40 %、80 %、50 %。傳統(tǒng)的PEMFC因?yàn)槭p極板的材料、工藝等問題,造成其體積和質(zhì)量較大,這增加了汽車的重量,縮小了汽車底盤地可用空間,影響了質(zhì)子交換膜燃料電池汽車的性能。因此開發(fā)體積小、成本低、制備工藝簡(jiǎn)單的雙極板對(duì)推進(jìn)質(zhì)子交換膜燃料電池的商業(yè)化應(yīng)用具有重要意義。金屬雙極板因其成本低、力學(xué)性能好、導(dǎo)電性、導(dǎo)熱性、體積相對(duì)易控等特點(diǎn),在PEMFC領(lǐng)域備受關(guān)注。但金屬雙極板在PEMFC環(huán)境中易生成鈍化膜,導(dǎo)致其接觸電阻增加。因此,如何在提高金屬雙極板耐蝕性的同時(shí),保持良好的導(dǎo)電性,是當(dāng)前對(duì)PEMFC研究的重點(diǎn)。本文綜述了石墨、復(fù)合材料和金屬雙極板制備工藝及表面改性方法。討論了雙極板及其表面碳化物涂層、金屬涂層和氮化物涂層的優(yōu)缺點(diǎn),并比較了這些涂層在PEMFC環(huán)境下的耐腐蝕性和界面接觸電阻性能。

    Abstract:

    In PEMFCs components, the bipolar plate is the most important part due to its high proportion of the cost, volume, and mass of PEMFC (45 %, 80 %, and 50 %).Because of the material and process problems of the bipolar plate, the volume and mass of the traditional graphite PEMFC are relatively large, which increases the weight of the vehicle, reduces the available space of the vehicle chassis, and affects the performance of the PEMFC vehicle. Therefore, the development of a lightweight, low-cost, simple preparation process for the bipolar plate is of great significance to promote its commercial application.The metal bipolar plate has attracted much attention in the PEMFC field because of its low cost, good mechanical properties, electrical conductivity, thermal conductivity, and relatively easy-to-control volume. However, in the PEMFC environment, the metal bipolar plate is easy to form a passivation film, which leads to an increase in its contact resistance. Therefore, improving the corrosion resistance of metal bipolar plates and maintaining good conductivity are the main focus of current research on PEMFC.Our review summarized the graphite, composite, and metal bipolar plate preparation process or surface modification methods, and discussed the advantages and disadvantages of bipolar plate or surface-covered carbide coatings, metal coatings, and nitride coatings. in addition, we compared the corrosion resistance and interfacial contact resistance performance of these coatings under the PEMFC environment.

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引用本文

王瑜,邵文婷,武上焜,楊巍.質(zhì)子交換膜燃料電池極板及其表面改性研究進(jìn)展[J].稀有金屬材料與工程,2024,53(3):902~932.[WangYu, ShaoWenting, WuShangkun, YangWei. Research progress on surface modification of bipolar plates for proton exchange membrane fuel cells[J]. Rare Metal Materials and Engineering,2024,53(3):902~932.]
DOI:10.12442/j. issn.1002-185X.20230088

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  • 收稿日期:2023-02-23
  • 最后修改日期:2023-07-08
  • 錄用日期:2023-07-28
  • 在線發(fā)布日期: 2024-03-27
  • 出版日期: 2024-03-20