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摻雜HfO2對鈦合金微弧氧化膜層特性的影響
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西南石油大學(xué)

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四川省科技計劃資助(2022YFSY0018);釩鈦資源綜合利用國家重點(diǎn)實驗室開放基金(2022P4FZG08A);四川省頁巖氣高效開采先進(jìn)材料制備技術(shù)工程研究中心開放基金(2022SCYYQKCCL007)


Effect of doping HfO2 on the properties of micro-arc oxidation film on titanium alloy
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Southwest Petroleum University

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Supported by Sichuan Science and Technology Program ;State Key Laboratory of Vanadium and Titanium Resources Comprehensive Utilization;Supported by the Open Fund of Sichuan Provincial Engineering Research Center of Advanced Materials Manufacturing Technology for Shale Gas High-efficient Exploitation

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    摘要:

    在電解液中添加HfO2對Ti-6Al-4V鈦合金進(jìn)行微弧氧化處理,通過表征微弧氧化膜表、截面形貌,膜層成分及電化學(xué)行為,并測量膜層厚度、硬度、粗糙度等參數(shù)來研究添加HfO2對鈦合金微弧氧化膜層特性的影響。結(jié)果表明:添加HfO2后,微弧氧化膜層主要成分是Al2TiO5、TiO2和γ-Al2O3。較合適濃度的HfO2能促進(jìn)成膜反應(yīng),改善微弧氧化膜的微觀結(jié)構(gòu),提高膜層的厚度、硬度并降低表面粗糙度,且膜層試樣具有雙層膜結(jié)構(gòu),膜層試樣的耐腐蝕性能好于原基體。HfO2濃度為3.0g/L時所獲得的微弧氧化膜層綜合性能最佳。

    Abstract:

    The Ti-6Al-4V titanium alloy was treated with micro-arc oxidation by adding HfO2 into the electrolyte. The effect of adding HfO2 on the characteristics of the micro-arc oxidation film of titanium alloy was studied by characterizing the surface and cross-section morphology of the micro-arc oxidation film, the composition of the film and the electrochemical behavior, and measuring the thickness, hardness, roughness and other parameters of the film. The results show that after adding HfO2, the main components of the micro-arc oxidation film are Al2TiO5,TiO2 and γ-Al2O3.The appropriate concentration of HfO2 can promote the film-forming reaction, improve the microstructure of the micro-arc oxidation film, improve the thickness and hardness of the film and reduce the surface roughness. The film sample has a double-layer film structure, and the corrosion resistance of the film sample is better than the original substrate. When the concentration of HfO2 is 3.0g/L, the comprehensive performance of the micro-arc oxidation coating is the best.

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王香潔,王平,劉毅,楊彪,伍婷.摻雜HfO2對鈦合金微弧氧化膜層特性的影響[J].稀有金屬材料與工程,2023,52(10):3452~3460.[Wang Xiangjie, Wang Ping, Liu Yi, Yang Biao, Wu Ting. Effect of doping HfO2 on the properties of micro-arc oxidation film on titanium alloy[J]. Rare Metal Materials and Engineering,2023,52(10):3452~3460.]
DOI:10.12442/j. issn.1002-185X.20230065

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  • 收稿日期:2023-02-10
  • 最后修改日期:2023-04-03
  • 錄用日期:2023-04-10
  • 在線發(fā)布日期: 2023-10-27
  • 出版日期: 2023-10-24