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幾種合金在450℃/23MPa超臨界水氧化環(huán)境中腐蝕行為研究
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Corrosion behavior of several alloys in supercritical water oxidation environment at 450℃/23MPa
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    摘要:

    采用X射線衍射儀、掃描電子顯微鏡等分析手段,對(duì)比研究了四種典型鎳基耐蝕合金在450 ℃/23 MPa下Na3PO4、Na2SO4、NaCl超臨界水溶液中的腐蝕行為。50 h后,合金表層均勻分布著短棒狀、針狀的腐蝕產(chǎn)物,主要組成為NiCr2O4,Cr2O3,NiO,Ni3(PO4)2,CrPO4和Na3PO4等。500 h后,腐蝕層的厚度明顯增大,依據(jù)腐蝕層厚度的增大速度,四種合金的耐蝕性順序?yàn)椋篨-1#>X-2#>625>C-276

    Abstract:

    The corrosion behavior of four typical Ni-based corrosion-resistant alloys in supercritical aqueous solution of Na3PO4, Na2SO4 and NaCl at 450 ℃/23 MPa was studied by using XRD, SEM, etc. After corrosion for 50 h, the surface of the alloys was covered with short rod-shaped and needle-shaped products mainly consisting of NiCr2O4,Cr2O3,NiO,Ni3(PO4)2,CrPO4 and Na3PO4. With the prolong of time, the thickness of the corrosion layers increased and the corrosion resistance was ranked as X-1#>X-2#>625>C-276

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王琳琳,侯坤磊,查向東,歐美瓊,馬穎澈.幾種合金在450℃/23MPa超臨界水氧化環(huán)境中腐蝕行為研究[J].稀有金屬材料與工程,2024,53(1):204~214.[Wang linlin, houkunlei, Zhaxiangdong, oumeiqiong, mayingche. Corrosion behavior of several alloys in supercritical water oxidation environment at 450℃/23MPa[J]. Rare Metal Materials and Engineering,2024,53(1):204~214.]
DOI:10.12442/j. issn.1002-185X.20230010

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  • 收稿日期:2023-01-07
  • 最后修改日期:2023-02-07
  • 錄用日期:2023-02-14
  • 在線發(fā)布日期: 2024-01-29
  • 出版日期: 2024-01-24