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Hf對(duì)一種鎳基高硼鑄造高溫合金凝固行為及疏松情況的影響
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北京鋼研高納科技股份有限公司

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國家科技重大專項(xiàng)(J2019-VI-0018-0133)


Effect of Hf on Solidification Behavior and Porosity in a Nickel-Based High-Boron Cast Superalloy
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Gaona Aero Material Co,Ltd

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    摘要:

    研究了Hf的添加對(duì)一種鎳基高硼鑄造高溫合金顯微組織、凝固行為、疏松情況的影響。顯微組織分析、差熱分析(DSC)、等溫凝固淬火試驗(yàn)結(jié)果顯示,Hf在合金的凝固過程中強(qiáng)烈偏析于枝晶間區(qū)域,并在凝固末期以Ni5Hf相的形式從殘余液相中析出;Hf的加入降低了合金的液/固相線溫度、γ/γ′共晶相和硼化物析出溫度,延緩了合金的凝固過程,加寬了凝固溫度范圍,顯著增大了γ/γ′共晶相的含量。自主設(shè)計(jì)并澆鑄一種薄壁管鑄件,滲透檢驗(yàn)結(jié)果顯示Hf的加入使得薄壁管的疏松明顯減少,合金的疏松傾向性顯著降低。

    Abstract:

    The effects of Hf addition on the microstructure, solidification behavior and porosity of a nickel-based high-boron cast superalloy were studied. The results of microstructure analysis, differential thermal analysis (DSC) and isothermal solidification quenching test showed that Hf segregated in interdendritic regions during the solidification process of the alloy, and precipitated from the residual liquid phase in the form of Ni5Hf phase at the end of the solidification process. The addition of Hf reduced the precipitation temperature of liquid/solidus , γ/γ′ eutectic phase and boride, delayed the solidification process of the alloy, widened the solidification temperature range from 166.3 ℃ to 200.5 ℃, and significantly increased the content of γ/γ′ eutectic phases. A thin-walled tube cast was independently designed by ourselves. Penetration test results showed that the addition of Hf significantly reduced the porosity of the thin-walled tube, and the tendency of porosity forming of the alloy was significantly reduced.

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侯杰,李尚平,韓少麗,郝志博,杜夢,駱合力. Hf對(duì)一種鎳基高硼鑄造高溫合金凝固行為及疏松情況的影響[J].稀有金屬材料與工程,2023,52(12):4147~4154.[Hou Jie, Li Shangping, Han Shaoli, Hao Zhibo, Du Meng, Luo Heli. Effect of Hf on Solidification Behavior and Porosity in a Nickel-Based High-Boron Cast Superalloy[J]. Rare Metal Materials and Engineering,2023,52(12):4147~4154.]
DOI:10.12442/j. issn.1002-185X.20230001

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  • 收稿日期:2023-01-02
  • 最后修改日期:2023-05-30
  • 錄用日期:2023-06-01
  • 在線發(fā)布日期: 2023-12-29
  • 出版日期: 2023-12-22