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超細(xì)鉬粉制備技術(shù)的研究現(xiàn)狀與進(jìn)展
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TG146.4+12

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國(guó)家自然科學(xué)基金資助


Research status and progress of preparation technology of ultrafine molybdenum powder
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Project Supported by National Natural Science Foundation of China

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    摘要:

    金屬鉬因低的熱膨脹系數(shù)、高溫強(qiáng)度、高彈性模量等特性,廣泛用于航空航天、軍工、石油化工以及核工業(yè)等尖端行業(yè),是推動(dòng)高科技領(lǐng)域發(fā)展不可或缺的材料。鉬粉作為鉬制品的基礎(chǔ)原料,其物化性質(zhì)與鉬制品的性能密切相關(guān)。相比于普通鉬粉,超細(xì)鉬粉具有更大的比表面積、更高的活性以及更低的燒結(jié)溫度。目前制備超細(xì)鉬粉的方法主要有熱還原法和熱分解法,熱還原法通過(guò)調(diào)整還原工藝達(dá)到阻止晶粒長(zhǎng)大的目的;而熱分解法的發(fā)展主要涉及到裝備的升級(jí)改造與工藝的優(yōu)化完善。本文著眼于超細(xì)鉬粉的制備工藝、反應(yīng)機(jī)理以及產(chǎn)物狀態(tài),重點(diǎn)分析了典型工藝的發(fā)展歷程和技術(shù)特點(diǎn),總結(jié)了超細(xì)鉬粉制備技術(shù)的研究現(xiàn)狀與進(jìn)展,提出當(dāng)前技術(shù)工藝所面臨的問(wèn)題以及未來(lái)的研究方向,以期為超細(xì)鉬粉制備工藝的發(fā)展與工業(yè)化應(yīng)用提供思路。

    Abstract:

    Due to its low coefficient of thermal expansion, high temperature strength, high elastic modulus and other characteristics, molybdenum metal is widely used in aerospace, military, petrochemical and nuclear industries and other cutting-edge industries, is an indispensable material to promote the development of high-tech fields. Molybdenum powder as the basic material of molybdenum products, its physicochemical properties are closely related to the properties of molybdenum products. Compared with ordinary molybdenum powder, superfine molybdenum powder has larger specific surface area, higher activity and lower sintering temperature. At present, the main methods for preparing ultrafine molybdenum powder are thermal reduction method and thermal decomposition method. Thermal reduction method can prevent grain growth by adjusting the reduction process. The development of thermal decomposition method mainly involves the upgrading of equipment and the optimization of process. In this paper, focusing on the preparation process, reaction mechanism and product state of superfine molybdenum powder, the development process and technical characteristics of the typical process were analyzed, the research status and progress of the preparation technology of superfine molybdenum powder were summarized, and the problems faced by the current technology and the future research direction were put forward, in order to provide ideas for the development and industrial application of the preparation technology of superfine molybdenum powder.

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杜勝敏,王慶相,張石明,王瑞芳,車(chē)玉思,何季麟.超細(xì)鉬粉制備技術(shù)的研究現(xiàn)狀與進(jìn)展[J].稀有金屬材料與工程,2024,53(1):270~280.[Du Shengmin, Wang Qingxiang, Zhang Shiming, Wang Ruifang, Che Yusi, He Jilin. Research status and progress of preparation technology of ultrafine molybdenum powder[J]. Rare Metal Materials and Engineering,2024,53(1):270~280.]
DOI:10.12442/j. issn.1002-185X.20220975

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  • 收稿日期:2022-12-15
  • 最后修改日期:2023-03-22
  • 錄用日期:2023-03-24
  • 在線發(fā)布日期: 2024-01-29
  • 出版日期: 2024-01-24