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Re含量對(duì)DD15單晶高溫合金顯微組織和持久性能的影響
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北京航空材料研究院 先進(jìn)高溫結(jié)構(gòu)材料重點(diǎn)實(shí)驗(yàn)室,北京 100095

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National Science and Technology Major Project(J2019-Ⅲ-0008-0052, 2017–VI–0002–0071)


Effect of Re Content on Mircrostructure and Stress Rupture Properties of DD15 Single Crystal Superalloy
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Science and Technology on Advanced High Temperature Structural Materials Laboratory, Beijing Institute of Aeronautical Materials, Beijing 100095, China

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National Science and Technology Major Project (2017-VI-0002-0071, J2019-Ⅲ-0008-0052)

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    摘要:

    在定向凝固爐中制備了3種不同Re含量(5%,6%,7%,質(zhì)量分?jǐn)?shù))、其它合金元素相同的第4代單晶高溫合金DD15,將其完全熱處理后在1100 ℃長(zhǎng)期時(shí)效1000 h,在1100 ℃/137 MPa條件下測(cè)試合金的持久性能。研究了Re含量對(duì)DD15單晶高溫合金組織穩(wěn)定性和持久性能的影響。結(jié)果表明,隨著Re含量增加,γ′相尺寸減小,其體積分?jǐn)?shù)和立方化程度稍有增加,長(zhǎng)期時(shí)效時(shí)γ′相粗化、筏排化速率和TCP相析出量增加,合金的組織穩(wěn)定性降低。合金的持久性能隨著Re含量增加而顯著降低。3種斷裂試樣中均發(fā)現(xiàn)了TCP相,其含量隨著Re含量增加而增多,這是合金持久性能隨Re含量增加而降低的主要原因。γ/γ′相界面位錯(cuò)網(wǎng)密度隨著Re含量增加而增加。Re元素在γ基體中有強(qiáng)烈的偏析傾向,分配比隨Re含量增加而顯著升高。隨著Re含量增加,合金的晶格錯(cuò)配度向負(fù)方向增加。

    Abstract:

    The fourth generation single crystal superalloy DD15 with Re content of 5wt%, 6wt%, and 7wt% was cast in the directionally solidified furnace, while other alloying elements were basically the same in content. The long term aging after full heat treatment was performed at 1100 °C for 1000 h. The stress rupture tests of the alloy were conducted under 1100 °C/137 MPa. The effect of Re content on the microstructure and stress rupture properties of the alloy was investigated. The results show that the size of γ′ phase decreases, the volume fraction and cubic degree of γ′ phase slightly increase with increase in Re content. After long term aging, the γ′ phase coarsens, and the drafting rate, precipitate rate and volume fraction of TCP phase are all improved with increase in Re content. With the increase in Re content, the microstructure stability and the stress rupture life of the alloy decline significantly. The three ruptured specimens all exhibit the presence of TCP phase. The amount of TCP phases increases greatly with increase in Re content. TCP phase can be the site of crack initiation. This is the main reason for the decrease in stress rupture life of the alloy with increase in Re content. The dislocation networks formed at the γ/γ′ interface of ruptured specimen turn denser with increase in Re content. Re has a strong segregation tendency in γ matrix. The partition ratio of Re rises significantly with increase in Re content. The lattice misfit of the alloy becomes larger toward negative with increase in Re content.

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引用本文

史振學(xué),劉世忠,岳曉岱,王志成,李嘉榮.Re含量對(duì)DD15單晶高溫合金顯微組織和持久性能的影響[J].稀有金屬材料與工程,2023,52(6):1977~1984.[Shi Zhenxue, Liu Shizhong, Yue Xiaodai, Wang Zhicheng, Li Jiarong. Effect of Re Content on Mircrostructure and Stress Rupture Properties of DD15 Single Crystal Superalloy[J]. Rare Metal Materials and Engineering,2023,52(6):1977~1984.]
DOI:10.12442/j. issn.1002-185X.20220960

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  • 收稿日期:2022-12-08
  • 最后修改日期:2023-02-23
  • 錄用日期:2023-03-14
  • 在線發(fā)布日期: 2023-07-03
  • 出版日期: 2023-06-30