2O3粉末在純Nb基體表面制備了Y改性的滲鋁涂層,研究了Y對(duì)涂層微觀組織和生長(zhǎng)機(jī)制的影響。結(jié)果表明,Y對(duì)涂層的相組成和NbAl3相的晶粒形態(tài)均無(wú)明顯影響。隨包埋劑中Y2O3添加量的增加,涂層表面的Y含量升高。Y改性后,涂層的生長(zhǎng)機(jī)制由受Al原子的沿晶擴(kuò)散控制轉(zhuǎn)變?yōu)槭蹵l原子的晶內(nèi)擴(kuò)散控制,降低了涂層的生長(zhǎng)速率,并使NbAl3相的柱狀晶區(qū)形成了<010>//ND和<110>//ND的兩種絲織構(gòu)。"/>

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Y對(duì)Nb基體表面包埋滲鋁涂層微觀組織和生長(zhǎng)機(jī)制的影響
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中國(guó)科學(xué)院金屬研究所

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國(guó)家重點(diǎn)研發(fā)計(jì)劃(2021YFC2202402);遼寧省自然科學(xué)基金(2019-MS-329)


Effects of Y modification on microstructure and growth mechanism of pack aluminizing coatings on Nb substrate
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Institute of Metal Research,Chinese Academy of Science

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    摘要:

    通過(guò)向包埋滲鋁劑中添加Y2O3粉末在純Nb基體表面制備了Y改性的滲鋁涂層,研究了Y對(duì)涂層微觀組織和生長(zhǎng)機(jī)制的影響。結(jié)果表明,Y對(duì)涂層的相組成和NbAl3相的晶粒形態(tài)均無(wú)明顯影響。隨包埋劑中Y2O3添加量的增加,涂層表面的Y含量升高。Y改性后,涂層的生長(zhǎng)機(jī)制由受Al原子的沿晶擴(kuò)散控制轉(zhuǎn)變?yōu)槭蹵l原子的晶內(nèi)擴(kuò)散控制,降低了涂層的生長(zhǎng)速率,并使NbAl3相的柱狀晶區(qū)形成了<010>//ND和<110>//ND的兩種絲織構(gòu)。

    Abstract:

    Y modified aluminizing coatings were prepared on pure Nb substrates by aluminizing in the pack mixtures with Y2O3 addtion. The effects of Y on the microstructure and growth mechanism of the coatings were studied. The results show that the Y has no obvious effect on the phase constitution of the coating and the grain morphology of NbAl3 phase. With the increase of Y2O3 content in the pack mixtures, the Y content on the coating surface increases. After Y modification, the growth mechanism of the coatings is changed from being controlled by the intergranular diffusion of Al atoms to being controlled by the intragranular diffusion of Al atoms, which reduces the growth rate of the coatings and contributes to the formation of two kinds of silk textures (<010>//ND and<110>//ND) in the columnar crystal area of NbAl3 phase.

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鄭力瑋,劉恩澤,鄭志,寧禮奎,佟健,譚政,李海英. Y對(duì)Nb基體表面包埋滲鋁涂層微觀組織和生長(zhǎng)機(jī)制的影響[J].稀有金屬材料與工程,2023,52(12):4117~4124.[Zheng Liwei, Liu Enze, Zheng Zhi, Ning Likui, Tong Jian, Tan Zheng, Li Haiying. Effects of Y modification on microstructure and growth mechanism of pack aluminizing coatings on Nb substrate[J]. Rare Metal Materials and Engineering,2023,52(12):4117~4124.]
DOI:10.12442/j. issn.1002-185X.20220882

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  • 收稿日期:2022-11-08
  • 最后修改日期:2023-03-27
  • 錄用日期:2023-04-07
  • 在線發(fā)布日期: 2023-12-29
  • 出版日期: 2023-12-22