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GH3230合金超溫循環(huán)氧化行為研究
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1.北京鋼研高納科技股份有限公司;2.鋼鐵研究總院

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Oxidative Behaviors of GH3230 Alloy Multi-Exposed to Ultra-high Temperatures
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1.Gaona Aero Material Co,Ltd;2.High Temperature Materials Research Institute,CISRI

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    摘要:

    試驗(yàn)測定了GH3230合金超溫至1200 ℃循環(huán)氧化動力學(xué),采用SEM、XRD和EPMA觀察分析氧化行為及其對近表面層成分、組織的影響。結(jié)果表明,1200 ℃循環(huán)熱暴露使合金持續(xù)產(chǎn)生氧化失重,失重速率由高變低再逐漸增加,但100次超溫產(chǎn)生的減薄量小于板材厚度波動的控制限度;熱暴露后表面殘留氧化物主要是Cr2O3和MnCr2O4;碳氧化產(chǎn)生的氣體形成的法向壓力、氧化物生長應(yīng)力的增大以及大溫差冷卻產(chǎn)生的熱應(yīng)力的疊加作用導(dǎo)致外層氧化膜的不斷開裂、剝離。同時,沿晶界發(fā)生明顯內(nèi)氧化,但氧化脫碳形成的Ni基固溶體層遠(yuǎn)大于內(nèi)氧化的深度,可抑制內(nèi)氧化物的致脆效應(yīng)。

    Abstract:

    The oxidation kinetics of GH3230 alloy was measured as a function of the cumulative time cyclically exposed upto 1200℃. The oxidation behaviors and the resulting composition and microstructure of the near surface layer were observed and analyzed by SEM, XRD and EPMA. It has been found that GH3230 alloy exhibits continuous oxidation weight loss during cyclic thermal exposures, and the weight loss rate decreases from the highest value to lowest level and then gradually increases with the thermal exposure time. Nevertheless, the alloy-thickness loss after 100 exposure cycles can be obviously less than the thickness-fluctuation limit of standardized plate products. The remaining oxides on the surface after heat exposure are mainly composed of Cr2O3 and MnCr2O4. The normal gas pressure produced by carbon oxidation, the increments of oxide growth stress and the thermal stress caused by over-temperature exposure lead to the cracking and spallation of the outer oxides. At mean time, internal oxidation occurs along grain boundaries significantly. While, it is worthy to note that the depth of the Ni-based solid solution layer tranformed through selective oxidation and oxidative decarbonization is always much larger than that of the internal oxidation. It indicates that the cracks initiated from the intergrannual oxides as the materials bearing tensile load will soon be blunted by in-front ductile FCC-stucture solid solution and therefore present negligible impact on the mechanical performance of GH3230 alloy.

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張亞瑋,沈宇,鞠泉,胥國華,張繼. GH3230合金超溫循環(huán)氧化行為研究[J].稀有金屬材料與工程,2023,52(9):3221~3229.[Zhang Yawei, Shen Yu, Ju Quan, Xu Guohuang, Zhang Ji. Oxidative Behaviors of GH3230 Alloy Multi-Exposed to Ultra-high Temperatures[J]. Rare Metal Materials and Engineering,2023,52(9):3221~3229.]
DOI:10.12442/j. issn.1002-185X.20220876

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歷史
  • 收稿日期:2022-11-06
  • 最后修改日期:2022-12-21
  • 錄用日期:2023-01-03
  • 在線發(fā)布日期: 2023-09-25
  • 出版日期: 2023-09-21