2Fe14B速凝薄帶;歧化時(shí)間;脫氫壓力;各向異性"/> 2Fe14BH1.04的含量,殘余母相能夠更好地將母相的織構(gòu)信息傳遞下去,使得新相Nd2Fe14B有很強(qiáng)的c軸織構(gòu),磁粉在歧化時(shí)間為40 min時(shí)各向異性達(dá)到最佳,DOA=0.55。而脫氫壓力主要作為晶體生長(zhǎng)的驅(qū)動(dòng)力,壓力在0.01 MPa時(shí)驅(qū)動(dòng)力過(guò)大,導(dǎo)致脫氫之后晶粒生長(zhǎng)方向隨機(jī),c軸織構(gòu)不明顯,生成的新相Nd2Fe14B的各向異性較弱;磁粉在脫氫壓力為0.03 Mpa時(shí)各向異性得到顯著增強(qiáng),DOA=0.53。"/>

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釹鐵硼磁粉HDDR工藝各向異性生成機(jī)理研究
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1.中國(guó)石油大學(xué)華東 材料科學(xué)與工程學(xué)院;2.中國(guó)石油大學(xué)華東 理學(xué)院

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山東省自然科學(xué)基金(ZR2020ME010);青島市科技發(fā)展計(jì)劃(22-3-7-cspz-9-nsh)


Anisotropic Properties of NdFeB Magnetic Powder Treated by HDDR Process
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1.China University of PetroleumEast China School of Materials Science and Engineering;2.China University of PetroleumEast China college of science

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    摘要:

    本文對(duì)釹鐵硼速凝薄帶進(jìn)行“氫化-歧化-脫氫-復(fù)合”工藝(HDDR)處理,研究了歧化時(shí)間、脫氫壓力對(duì)HDDR磁粉磁性能的影響及磁各向異性的產(chǎn)生機(jī)理。通過(guò)XRD對(duì)其進(jìn)行物相表征,SEM觀察微觀形貌及磁性能測(cè)試,結(jié)果表明:歧化時(shí)間決定了HD工藝后磁粉材料中歧化相和殘余母相Nd2Fe14BH1.04的含量,殘余母相能夠更好地將母相的織構(gòu)信息傳遞下去,使得新相Nd2Fe14B有很強(qiáng)的c軸織構(gòu),磁粉在歧化時(shí)間為40 min時(shí)各向異性達(dá)到最佳,DOA=0.55。而脫氫壓力主要作為晶體生長(zhǎng)的驅(qū)動(dòng)力,壓力在0.01 MPa時(shí)驅(qū)動(dòng)力過(guò)大,導(dǎo)致脫氫之后晶粒生長(zhǎng)方向隨機(jī),c軸織構(gòu)不明顯,生成的新相Nd2Fe14B的各向異性較弱;磁粉在脫氫壓力為0.03 Mpa時(shí)各向異性得到顯著增強(qiáng),DOA=0.53。

    Abstract:

    Effects of disproportionation time and dehydrogenation pressure on the magnetic properties and anisotropy of HDDR magnetic powders were studied. The phase structures of the samples were identified by X-ray powder diffraction. The microstructure was investigated using scanning electron microscope. The magnetic properties of NdFeB were measured by AMT-4A magnetic measuring instrument. The results showed that the disproportionation time determines the content of the disproportionated phase and the residual parentNd2Fe14BH1.04 phase in the material after the HD process. The residual parent Nd2Fe14BH1.04 can inherit the texture information of the original Nd2Fe14B phase, which results in strong c-axis texture of new phase Nd2Fe14B. When the disproportionation time extends to 40 min, the anisotropy of the magnetic powder reaches the maximum, DOA=0.55. The dehydrogenation pressure mainly acts as the driving force for the crystal growth. The low pressure of 0.01 Mpa will cause over large driving force, which leads to the weak anisotropy of the generated new phase Nd2Fe14B. The magnetic powder has the optimum anisotropy when the dehydrogenation pressure is at 0.03 Mpa, DOA=0.53.

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于濂清,劉科,張亞萍,朱海豐.釹鐵硼磁粉HDDR工藝各向異性生成機(jī)理研究[J].稀有金屬材料與工程,2023,52(11):3867~3872.[Yu Lianqing, Liu Ke, Zhang Yaping, Zhu Haifeng. Anisotropic Properties of NdFeB Magnetic Powder Treated by HDDR Process[J]. Rare Metal Materials and Engineering,2023,52(11):3867~3872.]
DOI:10.12442/j. issn.1002-185X.20220841

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  • 收稿日期:2022-10-26
  • 最后修改日期:2023-02-08
  • 錄用日期:2023-02-14
  • 在線發(fā)布日期: 2023-11-27
  • 出版日期: 2023-11-22