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彎曲形變及熱處理對(duì)純鎳N6焊縫晶界特征分布及腐蝕行為的影響
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蘭州城市學(xué)院

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TG146.1+5 TG456.2 TG156.93

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甘肅省科技重大專項(xiàng)計(jì)劃(145RTSA004),甘肅省高等學(xué)??蒲许?xiàng)目(2020A-128)


Effect of Bending Deformation and Heat Treatment on Grain Boundary Characteristic Distribution and Corrosion Behavior for Pure Nickel N6 Weld
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    摘要:

    對(duì)純鎳N6等離子弧焊縫進(jìn)行“U”形彎曲形變及熱處理加工,借助電子背散射衍射(EBSD)和取向成像顯微技術(shù)(OIM)對(duì)比分析Non-GBE、GBE樣品晶界特征分布(GBCD)及對(duì)腐蝕行為的影響。結(jié)果表明:焊縫經(jīng)“U”形彎曲形變+900℃退火10min后,低ΣCSL晶界比例提高到54.1%,并形成具有Σ3n取向關(guān)系的大尺寸晶粒團(tuán)簇;退火過(guò)程中再結(jié)晶形核點(diǎn)增加,晶粒尺寸下降到146 um。GBE樣品耐蝕性高于Non-GBE樣品,GBE樣品(0.2113 A·m-2)自腐蝕電流密小于Non-GBE樣品(0.8138 A·m-2),且GBE樣品的容抗弧半徑、阻抗模值|Z|、相位角θ均大于對(duì)應(yīng)Non-GBE樣品。兩種樣品表面均發(fā)生了點(diǎn)蝕,腐蝕行為概括為:腐蝕初期,C1-破壞樣品表面局部區(qū)域鈍化膜形成點(diǎn)蝕坑。隨浸泡時(shí)間延長(zhǎng),陽(yáng)極金屬附近Ni2+濃度達(dá)到飽和或過(guò)飽和狀態(tài),Ni2+與膜層中結(jié)合水反應(yīng)生成Ni(OH)2,部分Ni(OH)2脫水分解為NiO,組成的腐蝕產(chǎn)物膜沉積在樣品表面,阻止Cl-穿過(guò)腐蝕產(chǎn)物滲透到樣品表面,點(diǎn)蝕受到控制。

    Abstract:

    The pure nickel N6 plasma arc weld was subject to U-shaped bending deformation heat treatment.The grain boundary characteristic distribution (GBCD) of Non GBE and GBE samples and its influence on corrosion behavior were studied by grain boundary character distribution (EBSD) and orientation image microscopy (OIM). The results show that the proportion of lowΣCSL grain boundaries increase to more than 54.1% by the TMP after U-shaped bending deformation and subsequent annealing at 900℃ for 10 min, and simultaneously the large-size highly-twinned grain-cluster microstructure is formed.The recrystallization nucleation point increased and the grain size decreased to 146 um during annealing.The corrosion resistance of GBE sample is higher than that of Non GBE sample. The self corrosion current density of GBE sample is less than that of Non GBE sample, and the capacitive arc radius, impedance modulus and phase angle of GBE sample are greater than those of corresponding Non GBE samples.Pitting corrosion occurr on the surface of samples.The passivation film on the surface of the coating is destroyed by C1-in the solution and forms pitting pits at the initial stage.With the prolongation of immersion time, the concentration of Ni2+near the anode metal reaches saturation or supersaturation. the bound water in the corrosion product film reacts with Ni2+ forms Ni(OH)2, and then the Ni(OH)2 are dehydrated and decomposed into NiO.Corrosion products cover the surface of the sample and form a corrosion product film, which are composed of NiO and Ni(OH)2. The corrosion product film has a protective effect,which prevents Cl- from penetrating through the corrosion products to the sample surface and the pitting is controlled.

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柴廷璽,徐宏彤,晏麗琴,俞友軍,王志全.彎曲形變及熱處理對(duì)純鎳N6焊縫晶界特征分布及腐蝕行為的影響[J].稀有金屬材料與工程,2023,52(10):3590~3599.[Chai Tingxi, Xu Hongtong, Yan Liqin, Yu Youjun, Wang Zhiquan. Effect of Bending Deformation and Heat Treatment on Grain Boundary Characteristic Distribution and Corrosion Behavior for Pure Nickel N6 Weld[J]. Rare Metal Materials and Engineering,2023,52(10):3590~3599.]
DOI:10.12442/j. issn.1002-185X.20220790

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  • 收稿日期:2022-10-10
  • 最后修改日期:2022-11-14
  • 錄用日期:2022-11-24
  • 在線發(fā)布日期: 2023-10-27
  • 出版日期: 2023-10-24