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高熵合金高能束增材制造及性能的研究進展
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作者單位:

1.南昌航空大學 輕合金加工科學與技術(shù)國防重點學科實驗室;2.南昌航空大學;3.江西昌河航空工業(yè)有限公司

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中圖分類號:

V261;TB331

基金項目:

國家自然科學基金(52105451);江西省重大科技研發(fā)專項(20194ABC28001);江西省重點研發(fā)計劃重點項目(202112BBE51007);江西省重點研發(fā)計劃(20202BBEL53029);輕合金加工科學與技術(shù)國防重點學科實驗室開放課題研究基金(EG202003411)


Research progress of high entropy alloy high energy beam additive manufacturing and properties
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Affiliation:

1.National Defense Key Discipline Laboratory of Light Alloy Processing Science and Technology, Nanchang Hangkong University;2.Nanchang Hangkong University

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    摘要:

    高熵合金(HEA)是目前材料和工程科學領(lǐng)域的研究熱點。HEA不同于傳統(tǒng)合金,由多種主要元素組成,因此HEA成分數(shù)量可能大大超過傳統(tǒng)合金。HEA因其獨特“近/等摩爾比”的成分構(gòu)成,具備高硬度、抗氧化、抗腐蝕、耐高溫、耐磨等優(yōu)異的性能。增材制造(AM)與HEA結(jié)合可制備出高強度、高塑性、高度復雜幾何體的金屬零件。本文探討了目前廣泛使用的選區(qū)電子束熔化技術(shù)(SEBM)、選區(qū)激光熔化技術(shù)(SLM)、激光熔覆技術(shù)(LC)以及等離子熔覆技術(shù)(PC)。前兩者用于制備塊狀HEA,后兩者用于制備涂層HEA。SEBM制備的HEA延展性好,不易開裂;SLM制備的HEA成形精度、強度、表面光潔度高;LC制備的HEA熔覆層稀釋度極低,組織致密;PC制備的HEA熔覆層幾乎無氣孔、無裂紋。本文系統(tǒng)總結(jié)了4種不同AM方法的技術(shù)特點,以及制備的HEA相較于傳統(tǒng)鑄造技術(shù)在微觀結(jié)構(gòu)特征、力學和耐腐蝕性能方面的優(yōu)勢,并詳細介紹其內(nèi)在機理。本文為開發(fā)AM制備高熵合金的前沿技術(shù)提供理論思路。

    Abstract:

    High-entropy alloys (HEA) are a research hotspot in the field of materials and engineering sciences. Unlike traditional alloys, HEA is composed of many main elements. Thus, the number of HEA components may greatly exceed that of traditional alloys. HEA has excellent properties (e.g., high hardness, oxidation resistance, corrosion resistance, high-temperature resistance and wear resistance) due to its unique composition of "near/equimolar ratio." The combination of additive manufacturing (AM) and HEA can produce metal parts with high strength, high plasticity, and highly complex geometry. This paper discusses the currently widely used selective electron beam melting (SEBM), selective laser melting (SLM), laser cladding (LC), and plasma cladding (PC) technology. The first two are used to prepare bulk HEA. The last two are used to prepare the coated HEA. The HEA prepared by SEBM has good ductility and is not easy to crack. The HEA prepared by SLM has high forming accuracy, strength, and surface finish. The HEA cladding layer prepared by LC has a very low dilution degree and a dense structure. The HEA cladding layer prepared by PC has almost no pores and no cracks. This paper systematically summarizes the technical characteristics of four different AM methods, as well as the advantages of the prepared HEA compared with traditional casting techniques in terms of microstructural characteristics, mechanics and corrosion resistance, and introduces its intrinsic mechanism in detail. This paper provides theoretical ideas for the development of cutting-edge technologies for preparing high-entropy alloys by AM.

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郭義乾,郭正華,李智勇,汪廣平,劉奮成,曾一達.高熵合金高能束增材制造及性能的研究進展[J].稀有金屬材料與工程,2023,52(8):2965~2977.[Guo Yiqian, Guo Zhenghua, Li Zhiyong, Wang Guangping, Liu Fencheng, ZengYida. Research progress of high entropy alloy high energy beam additive manufacturing and properties[J]. Rare Metal Materials and Engineering,2023,52(8):2965~2977.]
DOI:10.12442/j. issn.1002-185X.20220581

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  • 收稿日期:2022-07-12
  • 最后修改日期:2022-09-16
  • 錄用日期:2022-09-21
  • 在線發(fā)布日期: 2023-08-28
  • 出版日期: 2023-08-24