2;MgO"/> 2體系的潤濕性和界面組織進行了研究。從熱力學(xué)角度討論了3個體系界面反應(yīng)產(chǎn)物的形成。結(jié)果表明,Al-8Si/不銹鋼的界面組織由Fe(Al,Si)3、Al7.2Fe1.8Si和Fe2Al5相組成,而Al-8Si/MgO和Al-8Si/TiO2體系的界面組織主要由不同形貌Al2O3相組成。3種體系的潤濕性測試結(jié)果表明,Al-8Si熔體在MgO上具有較好的非潤濕性能,其平衡潤濕角為124°。3種體系潤濕性的差異主要與界面產(chǎn)物的性質(zhì)和粗糙度有關(guān)。界面粗糙度測試結(jié)果表明,Al-8Si/MgO體系界面粗糙度最大,為1.46 μm,主要原因是界面反應(yīng)過程中Mg的蒸發(fā)破壞了界面反應(yīng)層的形貌,此外Ti的存在促進了Al-8Si/TiO2體系的界面反應(yīng),增加了界面反應(yīng)層的厚度,降低了平衡潤濕角。"/>

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1173 KAl-8Si二元合金對MgO、TiO2 和不銹鋼的潤濕作用
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1.蘭州理工大學(xué) 省部共建有色金屬先進加工與再利用國家重點實驗室,甘肅 蘭州 730050;2.蘭州理工大學(xué) 材料科學(xué)與工程學(xué)院,蘭州 730050;3.大連交通大學(xué) 材料科學(xué)與工程學(xué)院,大連 116028

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基金項目:

國家重點基礎(chǔ)研究發(fā)展計劃(No. 2018YFB2001800),國家自然科學(xué)基金項目(51961021, 52001152)


Wetting of MgO, TiO2 and Stainless Steel by Molten Al-8Si Binary Alloy at 1173 K
Author:
Affiliation:

1.State Key Laboratory of Advanced Processing and Recycling of Nonferrous Metals, Lanzhou University of Technology, Lanzhou 730050, China;2.School of Material Science and Engineering, Lanzhou University of Technology, Lanzhou 730050, China;3.School of Materials Science and Engineering, Dalian Jiaotong University, Dalian 116028, China

Fund Project:

National Key Research and Development Program (2018YFB2001800); National Natural Science Foundation of China (51961021, 52001152); Undergraduate Innovation and Entrepreneurship Training Program (DC2021011, DC2021018, DC2021036)

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    摘要:

    采用改良座滴法對Al-8Si/不銹鋼、Al-8Si/MgO和Al-8Si/TiO2體系的潤濕性和界面組織進行了研究。從熱力學(xué)角度討論了3個體系界面反應(yīng)產(chǎn)物的形成。結(jié)果表明,Al-8Si/不銹鋼的界面組織由Fe(Al,Si)3、Al7.2Fe1.8Si和Fe2Al5相組成,而Al-8Si/MgO和Al-8Si/TiO2體系的界面組織主要由不同形貌Al2O3相組成。3種體系的潤濕性測試結(jié)果表明,Al-8Si熔體在MgO上具有較好的非潤濕性能,其平衡潤濕角為124°。3種體系潤濕性的差異主要與界面產(chǎn)物的性質(zhì)和粗糙度有關(guān)。界面粗糙度測試結(jié)果表明,Al-8Si/MgO體系界面粗糙度最大,為1.46 μm,主要原因是界面反應(yīng)過程中Mg的蒸發(fā)破壞了界面反應(yīng)層的形貌,此外Ti的存在促進了Al-8Si/TiO2體系的界面反應(yīng),增加了界面反應(yīng)層的厚度,降低了平衡潤濕角。

    Abstract:

    The wettability and interface microstructures of Al-8Si/stainless steel, Al-8Si/MgO, and Al-8Si/TiO2 systems were investigated by a modified sessile drop method. The formation of interface products of three systems was discussed from the view of thermodynamics. Results show that the interface microstructure of Al-8Si/stainless steel is composed of Fe(Al,Si)3, Al7.2Fe1.8Si and Fe2Al5 phases, while that of Al-8Si/MgO and Al-8Si/TiO2 systems consists mainly of the Al2O3 phase with different morphologies and roughness. The wettability results indicate that the Al-8Si/MgO system exhibits a better non-wettability compared with the stainless steel and TiO2 substrates, whose equilibrium wetting angle is 124°. The wettability differences of the three systems are mainly related to the roughness and properties of interface products. The interface roughness tests show that the interface of Al-8Si/MgO system has the largest roughness of 1.46 μm, which is mainly due to the evaporation of Mg that destroys the morphology of the interface reaction layer during the interface reaction process. Furthermore, the existence of Ti promotes the interface reaction and increases the thickness of interface reaction layer and thus reduces the equilibrium wetting angle of Al-8Si/TiO2 system.

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畢廣利,齊珈晨,姜靜,林巧力,李元東,陳體軍,馬穎,管仁國.1173 KAl-8Si二元合金對MgO、TiO2 和不銹鋼的潤濕作用[J].稀有金屬材料與工程,2023,52(4):1251~1258.[Bi Guangli, Qi Jiachen, Jiang Jing, Lin Qiaoli, Li Yuandong, Chen Tijun, Ma Ying, Guan Renguo.Wetting of MgO, TiO2 and Stainless Steel by Molten Al-8Si Binary Alloy at 1173 K[J]. Rare Metal Materials and Engineering,2023,52(4):1251~1258.]
DOI:10.12442/j. issn.1002-185X.20220526

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  • 收稿日期:2022-06-17
  • 最后修改日期:2022-09-02
  • 錄用日期:2022-09-19
  • 在線發(fā)布日期: 2023-04-28
  • 出版日期: 2023-04-25