-1)和能量密度(2600 Wh kg-1)成為研究的熱點。硫資源豐富,無毒和環(huán)境友好等優(yōu)勢也使鋰硫電池成為最有前途的儲能體系之一。然而,仍然有硫的導電性差、多硫化物在電極之間來回“穿梭”和硫與其還原產物密度差異等問題制約其應用化發(fā)展。相關研究表明,過渡金屬硒化物具有良好的導電性?;谄錁O性特征,過渡金屬硒化物可以加速氧化還原反應動力學,抑制穿梭效應,改善鋰硫電池的電化學性能。本文主要綜述了過渡金屬硒化物在鋰硫電池正極材料以及隔膜等方面的應用,并且對過渡金屬硒化物在鋰硫電池應用的未來研究方向和發(fā)展趨勢提出展望。"/>

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過渡金屬硒化物在鋰硫電池中的應用
作者:
作者單位:

1.太原科技大學 材料科學與工程學院;2.太原科技大學機械工程學院

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基金項目:

山西省高等學校科技創(chuàng)新項目(項目號:2020L0354);太原科技大學科研啟動基金(項目號:20192035)


Transition metal selenides in lithium-sulfur batteries
Author:
Affiliation:

1.School of Materials Science and Engineering,Taiyuan University of Science and Technology;2.School of Mechanical Engineering,Taiyuan University of Science and Technology

Fund Project:

Science and Technology Innovation Project of Higher Education Institutions in Shanxi Province(2020L0354);Taiyuan University of Science and Technology Research Start-up Fund(2019035)

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    摘要:

    鋰硫電池因較高的理論比容量(1675 mAh g-1)和能量密度(2600 Wh kg-1)成為研究的熱點。硫資源豐富,無毒和環(huán)境友好等優(yōu)勢也使鋰硫電池成為最有前途的儲能體系之一。然而,仍然有硫的導電性差、多硫化物在電極之間來回“穿梭”和硫與其還原產物密度差異等問題制約其應用化發(fā)展。相關研究表明,過渡金屬硒化物具有良好的導電性?;谄錁O性特征,過渡金屬硒化物可以加速氧化還原反應動力學,抑制穿梭效應,改善鋰硫電池的電化學性能。本文主要綜述了過渡金屬硒化物在鋰硫電池正極材料以及隔膜等方面的應用,并且對過渡金屬硒化物在鋰硫電池應用的未來研究方向和發(fā)展趨勢提出展望。

    Abstract:

    Lithium-sulfur batteries have gotten to be a hot inquire about subject due to their tall hypothetical particular capacity (1675 mAh g-1) and energy density (2600 Wh kg-1). Focal points such as plenteous sulfur assets, non-toxicity and natural invitingness moreover make lithium-sulfur batteries one of the foremost promising vitality capacity frameworks. In any case, the destitute electrical conductivity of sulfur, the "transporting" of polysulfide between anodes and the contrast in thickness between sulfur and its diminishment items are still issues that restrain its application. Related studies have appeared that move metal selenides have great electrical conductivity. Based on their polar characteristics, move metal selenides can quicken the energy of redox responses, smother carry impacts, and make strides the electrochemical execution of lithium-sulfur batteries. This paper mainly reviews the applications of move metal selenides in lithium-sulfur battery cathode materials and stomachs, and presents an viewpoint on long run investigate course and advancement drift of move metal selenides in lithium-sulfur battery applications.

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郭錦,張怡軒,任家友,陳展,張敏剛,李占龍.過渡金屬硒化物在鋰硫電池中的應用[J].稀有金屬材料與工程,2023,52(8):2943~2952.[Guo Jin, Zhang Yixuan, Ren Jiayou, Chen Zhan, Zhang Mingang, Li Zhanlong. Transition metal selenides in lithium-sulfur batteries[J]. Rare Metal Materials and Engineering,2023,52(8):2943~2952.]
DOI:10.12442/j. issn.1002-185X.20220499

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  • 收稿日期:2022-06-08
  • 最后修改日期:2022-07-20
  • 錄用日期:2022-08-12
  • 在線發(fā)布日期: 2023-08-28
  • 出版日期: 2023-08-24